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CAS 34767-55-0

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Bis[(1,2-η)-cyclooctene](2,4-pentanedionato-κO2,κO4)rhodium

Description:
Bis[(1,2-η)-cyclooctene](2,4-pentanedionato-κO2,κO4)rhodium, with the CAS number 34767-55-0, is a coordination complex of rhodium. This compound features a rhodium center coordinated to two cyclooctene ligands and a bidentate 2,4-pentanedione ligand, which stabilizes the metal center through its oxygen donor atoms. The structure exhibits a unique η^2 coordination mode from the cyclooctene ligands, which contributes to its reactivity and potential applications in catalysis. The presence of the pentanedionato ligand enhances the solubility and stability of the complex in various solvents. This compound is of interest in organometallic chemistry and catalysis, particularly in reactions involving olefins. Its properties, such as melting point, solubility, and reactivity, can vary depending on the specific conditions and environment in which it is studied. Overall, this rhodium complex exemplifies the diverse chemistry of transition metal coordination compounds and their utility in synthetic applications.
Formula:C21H35O2Rh
InChI:InChI=1S/2C8H14.C5H7O2.Rh/c2*1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h2*1-2H,3-8H2;3H,1-2H3;/q;;-1;+1
InChI key:InChIKey=FGDJCPXNYBINDJ-UHFFFAOYSA-N
SMILES:CC1=O[Rh+]23([CH]4=[CH]2CCCCCC4)([CH]5=[CH]3CCCCCC5)O=C(C)[CH-]1
Synonyms:
  • (2,4-Pentanedionato)bis(h2-cyclooctene)rhodium
  • (2,4-Pentanedionato)bis(η<sup>2</sup>-cyclooctene)rhodium
  • (Acetylacetonato)bis(cyclooctene)rhodium
  • Acetylacetonatobis(Cyclooctene)Rhodium(I)
  • Bis(cyclooctene)(2,4-pentanedionato)rhodium
  • Bis(cyclooctene)rhodium acetylacetonate
  • Bis[(1,2-η)-cyclooctene](2,4-pentanedionato-κO<sup>2</sup>,κO<sup>4</sup>)rhodium
  • Cyclooctene, rhodium complex
  • Rhodium, bis[(1,2-h)-cyclooctene](2,4-pentanedionato-O,O')-
  • Rhodium, bis[(1,2-h)-cyclooctene](2,4-pentanedionato-kO,kO')-
  • See more synonyms
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