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CAS 35138-22-8

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Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) (1:1)

Description:
Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) is a coordination compound featuring rhodium in a +1 oxidation state, complexed with two molecules of cyclooctadiene, which is a diene that can coordinate to metals in a η^4 fashion. The tetrafluoroborate anion serves as a counterion, providing stability to the complex. This compound is characterized by its unique geometry and electronic properties, which arise from the interaction between the rhodium center and the cyclooctadiene ligands. The presence of the tetrafluoroborate ion contributes to its solubility in polar solvents. Rhodium complexes are often studied for their catalytic properties, particularly in organic synthesis and hydrogenation reactions. The specific structure of this compound allows for interesting reactivity patterns and potential applications in catalysis. Additionally, the compound's stability and reactivity can be influenced by factors such as temperature, solvent, and the presence of other ligands or substrates. Overall, this compound exemplifies the rich chemistry associated with transition metal complexes.
Formula:C16H24Rh·BF4
InChI:InChI=1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1
InChI key:InChIKey=NBGSCPNNKGVTKU-UHFFFAOYSA-N
SMILES:[Rh+]123456([CH]7=[CH]1CC[CH]2=[CH]3CC7)[CH]8=[CH]4CC[CH]5=[CH]6CC8.[B+3]([F-])([F-])([F-])[F-]
Synonyms:
  • (1Z,5Z)-cycloocta-1,5-diene
  • 1,5-Cyclooctadiene, rhodium complex
  • Bis(1,5-Cyclooctadien)Rhodium(I) Tetrafluoroborate
  • Bis(1,5-Cyclooctadiene)Rhodium Tetrafluoroborate
  • Bis(1,5-cyclooctadiene)(tetrafluoroborato)rhodium
  • Bis(1,5-cyclooctadiene)rhodium(1+) tetrafluoroborate
  • Bis(1,5-cyclooctadiene)rhodium(1+) tetrafluoroborate(1-)
  • Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate Also available as trifluoromethanesulfonate and hexafluorophosphate
  • Bis(1,5-cyclooctadienyl)rhodium tetrafluoroborate
  • Bis(Cycloocta-1,5-Dien)Rhodium(I)-Tetrafluoroborate
  • See more synonyms
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