CAS 352-13-6: 4-Fluorophenylmagnesium bromide

Description: 4-Fluorophenylmagnesium bromide is an organometallic compound classified as a Grignard reagent, which is characterized by the presence of a magnesium atom bonded to a phenyl group that is substituted with a fluorine atom. This compound typically appears as a colorless to light yellow solution when dissolved in appropriate solvents, such as diethyl ether or tetrahydrofuran. It is highly reactive, particularly with water and protic solvents, leading to the release of hydrocarbons and the formation of the corresponding hydrocarbon and magnesium hydroxide. The presence of the fluorine atom enhances the electrophilic character of the phenyl ring, making it useful in various organic synthesis reactions, including nucleophilic substitutions and coupling reactions. Due to its reactivity, 4-fluorophenylmagnesium bromide must be handled under an inert atmosphere to prevent decomposition and moisture contamination. Safety precautions are essential, as it can be hazardous and corrosive, necessitating the use of appropriate personal protective equipment when handling.

Formula: C₆H₄BrFMg

InChI: InChI=1S/C6H4F.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1

InChI key: InChIKey=QYBFFRXNNFXREA-UHFFFAOYSA-M

SMILES: FC1=CC=C([Mg]Br)C=C1

Synonyms:

• (4-Fluorophenyl)-magnesium bromide
• (4-Fluorophenyl)Magnesium(1+) Bromide
• Benzene, fluoro-, magnesium complex
• Bromo(4-Fluorophenyl)Magnesium
• Bromo(p-fluorophenyl)magnesium
• Magnesium Bromide Fluorobenzenide
• Magnesium, bromo(4-fluorophenyl)-
• Magnesium, bromo(p-fluorophenyl)-
• p-Fluorophenylmagnesium bromide

4-Fluorophenylmagnesium Bromide (ca. 19% in Tetrahydrofuran, ca. 1.0mol/L)

CAS: 352-13-6

• Formula: C₆H₄BrFMg
• Color and Shape: Liquid
• Molecular weight: 199.31

4-Fluorophenylmagnesium bromide 1M solution in THF

CAS: 352-13-6

• Color and Shape: Liquid
• Molecular weight: 199.30g/mol

4-Fluorophenylmagnesium bromide, 2M in diethyl ether

CAS: 352-13-6

• Molecular weight: 199.30g/mol

4-Fluorophenylmagnesium bromide, 2M solution in diethyl ether, AcroSeal™

CAS: 352-13-660-29-7

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. …

• Formula: C₆H₄BrFMg
• Color and Shape: Clear to turbid yellow to brown, Solution, May develop some turbidity or precipitate
• Molecular weight: 199.31

4-Fluorophenylmagnesium bromide 1M in Tetrahydrofuran

CAS: 352-13-6

• Color and Shape: Liquid
• Molecular weight: 199.30499267578125

4-Fluorophenylmagnesium bromide solution - 1M in THF

CAS: 352-13-6

4-Fluorophenylmagnesium bromide solution - 1M in THF is a reactive substance. It is used for …

• Formula: C₆H₄BrFMg
• Purity: Min. 95%
• Color and Shape: Clear Liquid
• Molecular weight: 199.3 g/mol