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CAS 36309-88-3

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Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium dichloride

Description:
Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium dichloride, commonly referred to as Ru(dpp)3Cl2, is a coordination complex of ruthenium with notable photophysical and electrochemical properties. This compound features a central ruthenium ion coordinated to three bidentate ligands, 4,7-diphenyl-1,10-phenanthroline, which enhances its stability and solubility in various solvents. Ru(dpp)3Cl2 is characterized by its intense luminescence, making it valuable in applications such as photochemistry, photodynamic therapy, and as a luminescent probe in biological systems. The dichloride component indicates the presence of two chloride ions, which can participate in ligand exchange reactions. Additionally, the compound exhibits interesting redox behavior, allowing it to act as an electron transfer mediator. Its unique structural and electronic properties make it a subject of extensive research in fields like materials science and biochemistry, particularly in the development of light-harvesting systems and sensors. Overall, Ru(dpp)3Cl2 is a versatile compound with significant implications in both fundamental and applied chemistry.
Formula:C72H48N6Ru·2Cl
InChI:InChI=1S/3C24H16N2.2ClH.Ru/c3*1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;;;/h3*1-16H;2*1H;/q;;;;;+2/p-2
InChI key:InChIKey=SKZWFYFFTOHWQP-UHFFFAOYSA-L
SMILES:[Ru+2]123([N]=4C=5C=6[N]1=CC=C(C6C=CC5C(=CC4)C7=CC=CC=C7)C8=CC=CC=C8)([N]=9C=%10C=%11[N]2=CC=C(C%11C=CC%10C(=CC9)C%12=CC=CC=C%12)C%13=CC=CC=C%13)[N]=%14C=%15C=%16[N]3=CC=C(C%16C=CC%15C(=CC%14)C%17=CC=CC=C%17)C%18=CC=CC=C%18.[Cl-]
Synonyms:
  • 1,10-Phenanthroline, 4,7-diphenyl-, ruthenium complex
  • Bathophenanthroline ruthenium chloride
  • RuDPP
  • Ruthenium (II) tris(4,7-diphenyl-1,10-phenanthroline) dichloride
  • Ruthenium(2+) Chloride - 4,7-Diphenyl-1,10-Phenanthroline (1:2:3)
  • Ruthenium(2+), tris(4,7-diphenyl-1,10-phenanthroline-N<sup>1</sup>,N<sup>10</sup>)-, dichloride, (OC-6-11)-
  • Ruthenium(2+), tris(4,7-diphenyl-1,10-phenanthroline-κN<sup>1</sup>,κN<sup>10</sup>)-, chloride (1:2), (OC-6-11)-
  • Ruthenium(2+), tris(4,7-diphenyl-1,10-phenanthroline-κN<sup>1</sup>,κN<sup>10</sup>)-, dichloride, (OC-6-11)-
  • Tris(4,7-diphenyl-1,10-phenanthrolin)ruthenium(II) dichloride complex
  • Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium dichloride
  • See more synonyms
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