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CAS 364732-88-7

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(R)-Phanephos

Description:
(R)-Phanephos is a chiral phosphine ligand commonly used in asymmetric synthesis and catalysis. It is characterized by its ability to coordinate with transition metals, facilitating various chemical reactions, particularly in the field of organometallic chemistry. The structure of (R)-Phanephos includes a phosphine group attached to a biphenyl backbone, which contributes to its steric and electronic properties. This ligand is known for its effectiveness in promoting enantioselective reactions, making it valuable in the synthesis of chiral compounds. Its chirality allows for the preferential formation of one enantiomer over another, which is crucial in pharmaceutical applications where the activity of a drug can depend on its stereochemistry. Additionally, (R)-Phanephos is soluble in organic solvents, enhancing its utility in various reaction conditions. Overall, its unique properties make (R)-Phanephos a significant compound in modern synthetic chemistry, particularly in the development of new catalytic processes.
Formula:C40H34P2
InChI:InChI=1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2
InChI key:InChIKey=GYZZZILPVUYAFJ-UHFFFAOYSA-N
SMILES:P(C=1C=2CCC=3C=C(P(C4=CC=CC=C4)C5=CC=CC=C5)C(CCC(C1)=CC2)=CC3)(C6=CC=CC=C6)C7=CC=CC=C7
Synonyms:
  • (R)-Phanephos
  • stereoisomer of 1,1′-(Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenylphosphine]
  • (R)-PhanePHOS
  • Phosphine, 1,1′-(tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenyl-, stereoisomer
  • Phosphine, tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[diphenyl-, stereoisomer
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