CAS 374067-51-3

Ruthenium, bis(acetato-κO,κO′)[[(1R)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[diphenylphosphine-κP]]-, (OC-6-22)-

Description:

Ruthenium, bis(acetato-κO,κO′)[[(1R)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[diphenylphosphine-κP]]-, (OC-6-22) is a coordination compound featuring ruthenium as the central metal atom. This complex is characterized by its bis(acetato) ligands, which are coordinated through oxygen atoms, and a chiral binaphthyl-derived ligand that imparts stereochemical properties. The presence of diphenylphosphine ligands enhances the electronic properties and stability of the complex. The compound exhibits potential applications in catalysis, particularly in asymmetric synthesis, due to its chiral nature. Its structural features contribute to its reactivity and selectivity in various chemical reactions. Additionally, the complex's solubility and stability in different solvents can vary, influencing its practical applications in synthetic chemistry. Overall, this ruthenium complex exemplifies the intricate interplay between metal coordination, ligand design, and stereochemistry in organometallic chemistry.

Formula: C₄₈H₄₆O₄P₂Ru

InChI: InChI=1S/C44H40P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-12,19-26,29-32H,13-18,27-28H2;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key: InChIKey=HZRBASMTZGJUJU-UHFFFAOYSA-L

SMILES: CC=1[O-][Ru+2]23([P](C=4C(C=5C([P]2(C6=CC=CC=C6)C7=CC=CC=C7)=CC=C8C5CCCC8)=C9C(=CC4)CCCC9)(C%10=CC=CC=C%10)C%11=CC=CC=C%11)([O-]C(C)=O3)O1

Synonyms:

• (R)-Ru(OAc)2(H8-BINAP)
• Diacetato[(R)-(+)-2,2'-Bis(Diphenylphosphino)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-Binaphthy]Ruthenium(Ii)
• Diacetato[(R)-(+)-2,2’-bis(diphenylphosphino)-5,5’,6,6’,7,7’,8,8’-octahydro-1,1’-binaphthy]ruthenium(II)
• Diacetato[(R)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]ruthenium(II)
• Ruthenium, bis(acetato-κO,κO′)[[(1R)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[diphenylphosphine-κP]]-, (OC-6-22)-

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)₂[(R)-H₈-binap]

CAS: 374067-51-3

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]

Formula: C₄₈H₄₆O₄P₂Ru

Color and Shape: olive pwdr.

Molecular weight: 849.89

Ref: 08-44-0166

(R)-Ru(OAc)2(H8-BINAP)

CAS: 374067-51-3

Formula: C₄₈H₄₈O₄P₂Ru

Purity: 98%

Color and Shape: Solid

Molecular weight: 851.9098

Ref: IN-DA003CBW

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II)

CAS: 374067-51-3

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II)

Purity: 98%

Molecular weight: 851.93g/mol

Ref: 54-IN12947