CAS 37595-74-7

N-Phenyltrifluoromethanesulfonimide

Description:

N-Phenyltrifluoromethanesulfonimide, with the CAS number 37595-74-7, is a sulfonamide compound characterized by the presence of a trifluoromethanesulfonyl group attached to a phenyl ring. This compound is known for its high thermal stability and excellent solubility in polar aprotic solvents, making it useful in various chemical applications, particularly in organic synthesis and as a reagent in the preparation of ionic liquids. Its trifluoromethyl group contributes to its strong electron-withdrawing properties, enhancing its reactivity in nucleophilic substitution reactions. Additionally, N-Phenyltrifluoromethanesulfonimide exhibits low toxicity and is considered a non-hygroscopic solid, which is advantageous for handling and storage. The compound's unique properties make it a valuable tool in the development of new materials and in the field of catalysis, where it can facilitate various chemical transformations. Overall, its distinctive characteristics position it as a significant compound in both academic research and industrial applications.

Formula: C₈H₅F₆NO₄S₂

InChI: InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H

InChI key: InChIKey=DIOHEXPTUTVCNX-UHFFFAOYSA-N

SMILES: N(S(C(F)(F)F)(=O)=O)(S(C(F)(F)F)(=O)=O)C1=CC=CC=C1

Synonyms:

• 1,1,1-Trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
• 1,1,1-trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
• Methanesulfonamide, 1,1,1-trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]-
• N,N-Bis(trifluoromethanesulfonyl)aniline
• N,N-Bis(trifluoromethanesulphonyl)aniline
• N,N-Bis(trifluoromethylsulfonyl)aniline
• N,N-Bis(trifluoromethylsulfonyl)phenylamine
• N-Phenyl-N-(trifluoromethanesulfonyl)trifluoromethanesulfonamide
• N-Phenyl-N-[(trifluoromethyl)sulfonyl]trifluoromethanesulfonamide
• N-Phenyl-bis(trifluoromethanesulfonimide)
• N-Phenylbis(trifluoromethanesulfonimide)
• N-Phenylbis(trifluoromethanesulfonyl)imide
• N-Phenyltriflimide
• N-Phenyltrifluoromethanesulfonimide
• N-Phenyltrifluoromethanesulphonimide
• N-Phenyltrifluoromethylsulfonimide
• N-phenyl-bis (trifluoromethanesulfonyl) imide
• NSC 240874
• PhNTf₂
• Phenyl bis((trifluoromethyl)sulfonyl)amine
• Phenyl triflimide

N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]

CAS: 37595-74-7

Formula: C₈H₅F₆NO₄S₂

Purity: >98.0%(GC)

Color and Shape: White to Almost white powder to crystal

Molecular weight: 357.24

Ref: 3B-P1257

N-Phenylbis(trifluoromethanesulfonimide), 99%

CAS: 37595-74-7

N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselect

Formula: C₈H₅F₆NO₄S₂

Purity: 99%

Color and Shape: White to pale cream, crystalline solid

Molecular weight: 357.24

Ref: 02-L12531

N,N-Bis(trifluoromethylsulfonyl)aniline

CAS: 37595-74-7

Formula: C₈H₅F₆NO₄S₂

Purity: 96%

Color and Shape: Solid

Molecular weight: 357.2500

Ref: IN-DA0035B0

N,N-Bis(trifluoromethylsulphonyl)aniline

CAS: 37595-74-7

N,N-Bis(trifluoromethylsulphonyl)aniline

Formula: C₈H₅F₆NO₄S₂

Purity: 98%

Color and Shape: beige solid

Molecular weight: 357.25g/mol

Ref: 54-PC6227

N-Phenyl-bis(trifluoromethanesulfonimide)

CAS: 37595-74-7

Formula: C₈H₅F₆NO₄S₂

Purity: ≥ 97.0%

Color and Shape: White to off-white crystalline powder

Molecular weight: 357.25

Ref: 7W-GX3512

N-Phenyl bis-trifluoromethane sulfonimide

CAS: 37595-74-7

Formula: C₈H₅F₆NO₄S₂

Purity: 98.0%

Color and Shape: Solid, Chunks or Crystalline Powder

Molecular weight: 357.24

Ref: 10-F024773

N-Phenylbis(trifluoromethanesulfonamide)

Controlled Product

CAS: 37595-74-7

Stability Moisture Sensitive
Applications N-Phenylbis(trifluoromethanesulfonamide) is used in the enantioselective synthesis of β-amino acids via the Mannich reaction. Used in the synthesis of sphingosine 1-phosphate-1 receptor agonists useful in pharmaceutical application.
References Asano, M. et al.: Tetra. Asymm., 24, 449 (2013);

Formula: C₈H₅F₆NO₄S₂

Color and Shape: Neat

Molecular weight: 357.25

Ref: TR-P319780

N-Phenylbistrifluoromethanesulfonimide

CAS: 37595-74-7

N-Phenylbistrifluoromethanesulfonimide (NPBF) is a nitro compound that has been synthesized in an asymmetric synthesis. The chemical stability of NPBF is advantageous for the preparation of fluorescence probes. It has been used to study the structure and function of proteins, such as dopamine receptors, which are important in autoimmune diseases and metabolic disorders. A x-ray diffraction data study of NPBF was performed on tissue culture cells with human serum. This compound has shown a high affinity for Jak2 V617F mutants and organic chemists have investigated its use as a palladium-catalyzed coupling agent.

Formula: C₈H₅F₆NO₄S₂

Purity: Min. 95%

Color and Shape: White Powder

Molecular weight: 357.25 g/mol

Ref: 3D-FP11247