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CAS 38465-86-0

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1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate

Description:
1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate is a coordination complex featuring iridium as the central metal atom, coordinated by a cyclooctadiene ligand and two methyldiphenylphosphine ligands. This compound is characterized by its unique structure, which includes a cyclooctadiene ring that provides a stable environment for the iridium center, enhancing its reactivity and catalytic properties. The presence of the hexafluorophosphate counterion contributes to the compound's solubility in polar solvents and its stability under various conditions. Typically, such complexes exhibit interesting electronic properties due to the metal-ligand interactions, making them valuable in catalysis, particularly in organic transformations and polymerization processes. The phosphine ligands can influence the electronic characteristics of the iridium center, affecting its reactivity and selectivity in catalytic applications. Overall, this compound is of interest in both academic research and industrial applications due to its potential in facilitating various chemical reactions.
Formula:C36H46F6IrP3
InChI:InChI=1/2C13H13P.C8H12.2CH3.F5P.FH.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;;;1-6(2,3,4)5;;/h2*2-11H,1H3;1-2,7-8H,3-6H2;2*1H3;;1H;/q;;;;;;;-1/p+1/b;;2-1-,8-7-;;;;;/rC28H34IrP2.C8H12.F5P.FH/c1-29(2,30(3,25-17-9-5-10-18-25)26-19-11-6-12-20-26)31(4,27-21-13-7-14-22-27)28-23-15-8-16-24-28;1-2-4-6-8-7-5-3-1;1-6(2,3,4)5;/h5-24,30-31H,1-4H3;1-2,7-8H,3-6H2;;1H/q+1;;;/p-1/b;2-1-,8-7-;;
Synonyms:
  • (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
  • (1Z,5Z)-cycloocta-1,5-diene
  • Dimethyl-Bis(Methyl-Diphenyl-Phosphoranyl)Iridium
  • Pentafluorophosphorane
  • Fluoride
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