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CAS 38596-61-1

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Carbonyl(2,2,2-trifluoroacetato-κO)(2,2,2-trifluoroacetato-κO,κO′)bis(triphenylphosphine)ruthenium

Description:
Carbonyl(2,2,2-trifluoroacetato-κO)(2,2,2-trifluoroacetato-κO,κO′)bis(triphenylphosphine)ruthenium, with CAS number 38596-61-1, is a coordination complex of ruthenium featuring two 2,2,2-trifluoroacetate ligands and two triphenylphosphine ligands. This compound exhibits characteristics typical of transition metal complexes, including a central ruthenium atom that can adopt various oxidation states, influencing its reactivity and stability. The presence of the trifluoroacetate ligands imparts unique electronic properties due to the electronegative fluorine atoms, which can enhance the complex's solubility in organic solvents and affect its coordination behavior. The triphenylphosphine ligands contribute to the steric bulk and electronic properties of the complex, making it suitable for various catalytic applications, particularly in organic synthesis and coordination chemistry. Additionally, the carbonyl group in the structure indicates potential reactivity in carbonylation reactions. Overall, this compound is of interest in the fields of organometallic chemistry and catalysis due to its unique ligand environment and the versatile nature of ruthenium as a catalyst.
Formula:C41H30F6O5P2Ru
InChI:InChI=1S/2C18H15P.2C2HF3O2.CO.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*3-2(4,5)1(6)7;1-2;/h2*1-15H;2*(H,6,7);;/q;;;;;+2/p-2
InChI key:InChIKey=FDSSZHDREYJHRM-UHFFFAOYSA-L
SMILES:[P]([Ru+2]1([P](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)([O-]C(C(F)(F)F)=O)(C#O)[O-]C(C(F)(F)F)=O1)(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
Synonyms:
  • Ruthenium, carbonyl(trifluoroacetato-κO)(trifluoroacetato-κO,κO′)bis(triphenylphosphine)-
  • Ruthenium, carbonyl(trifluoroacetato-O)(trifluoroacetato-O,O′)bis(triphenylphosphine)-
  • Ruthenium, carbonyl(2,2,2-trifluoroacetato-κO)(2,2,2-trifluoroacetato-κO,κO′)bis(triphenylphosphine)-
  • Acetic acid, trifluoro-, ruthenium complex
  • Carbonyl(2,2,2-trifluoroacetato-κO)(2,2,2-trifluoroacetato-κO,κO′)bis(triphenylphosphine)ruthenium
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