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CAS 38625-54-6

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Tris(2,2,6,6,-tetramethyl-3,5-heptanedionato)ruthenium (III)

Description:
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ruthenium(III), commonly referred to as Ru(tmhd)3, is a coordination complex of ruthenium with notable characteristics. It features a central ruthenium ion coordinated to three bidentate ligands, specifically 2,2,6,6-tetramethyl-3,5-heptanedione (tmhd), which enhances its stability and solubility in organic solvents. This compound typically exhibits a dark red to purple color and is known for its thermal stability and relatively low volatility. Ru(tmhd)3 is often utilized in various applications, including catalysis, organic synthesis, and as a precursor in the deposition of ruthenium films. Its electronic properties are influenced by the ligand field created by the tmhd ligands, which can affect its reactivity and interaction with other chemical species. Additionally, the steric bulk of the ligands contributes to the compound's unique properties, making it a subject of interest in both academic and industrial research. Safety precautions should be taken when handling this compound, as with many metal complexes, due to potential toxicity.
Formula:C33H57O6Ru
InChI:InChI=1/3C11H20O2.Ru/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
SMILES:CC(C)(C)C(=CC(=O)C(C)(C)C)O.CC(C)(C)C(=CC(=O)C(C)(C)C)O.CC(C)(C)C(=CC(=O)C(C)(C)C)O.[Ru]
Synonyms:
  • Ruthenium iii tetramethylheptanedionate
  • Ruthenium(+3) Cation
  • (Z)-2,2,6,6-tetramethyl-5-oxo-hept-3-en-3-olate
  • Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ruthenium
  • Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ruthenium(Ⅲ)
  • Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ruthenium(III)
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