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CAS 387868-06-6

:

(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldi(bis-3,5-CF3-Ph2)P

Description:
The chemical substance with the name "(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldi(bis-3,5-CF3-Ph2)P" and CAS number "387868-06-6" is a chiral phosphine compound that features a ferrocenyl moiety, which contributes to its unique electronic and steric properties. This compound is characterized by its complex structure, which includes a central phosphorus atom bonded to multiple aromatic groups, enhancing its potential as a ligand in various catalytic applications, particularly in asymmetric synthesis. The presence of trifluoromethyl groups on the phenyl rings increases the electron-withdrawing character, influencing the reactivity and stability of the compound. Additionally, the chirality of the molecule allows for selective interactions in catalytic processes, making it valuable in the development of enantioselective reactions. Its unique combination of properties positions it as a significant compound in organometallic chemistry and catalysis, particularly in the context of transition metal complexes.
Formula:C46H32F12FeP2
InChI:InChI=1/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m0../s1
SMILES:C[C@@H](C1C=CC=C1c1ccccc1P(c1ccccc1)c1ccccc1)P(c1cc(cc(c1)C(F)(F)F)C(F)(F)F)c1cc(cc(c1)C(F)(F)F)C(F)(F)F.C1=C[CH]C=C1.[Fe]
Synonyms:
  • Walphos SL-WOO1-1
  • 1,2,3,4,5-cyclopentanepentayl, compd. with 1-[(1S)-1-[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl]-2-[2-(diphenylphosphino)phenyl]-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
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