CAS 38951-97-2

(SP-4-1)-Bis[1,2-bis(4-methoxyphenyl)-1,2-ethenedithiolato(2-)-κS1,κS2]nickel

Description:

(SP-4-1)-Bis[1,2-bis(4-methoxyphenyl)-1,2-ethenedithiolato(2-)-κS1,κS2]nickel, with the CAS number 38951-97-2, is a coordination compound featuring nickel as the central metal ion coordinated to a bidentate ligand. The ligand consists of two 1,2-bis(4-methoxyphenyl)-1,2-ethenedithiolato units, which provide sulfur donor atoms for coordination. This compound typically exhibits a square planar geometry around the nickel center, a common arrangement for d8 metal complexes. The presence of methoxy groups on the phenyl rings enhances the solubility and stability of the compound in organic solvents. Additionally, the electronic properties of the methoxy substituents can influence the redox behavior and optical characteristics of the complex. Such compounds are of interest in various fields, including materials science and organic electronics, due to their potential applications in organic semiconductors and as precursors for more complex metal-organic frameworks. The specific stereochemistry and electronic interactions can lead to unique physical and chemical properties, making them valuable for research and development.

Formula: C₃₂H₂₈NiO₄S₄

InChI: InChI=1S/2C16H16O2S2.Ni/c2*1-17-13-7-3-11(4-8-13)15(19)16(20)12-5-9-14(18-2)10-6-12;/h2*3-10,19-20H,1-2H3;/q;;+4/p-4

InChI key: InChIKey=WJDQFPDQIBNMCX-UHFFFAOYSA-J

SMILES: O(C)C1=CC=C(C=2S[Ni]3(SC(=C(S3)C4=CC=C(OC)C=C4)C5=CC=C(OC)C=C5)SC2C6=CC=C(OC)C=C6)C=C1

Synonyms:

• (SP-4-1)-Bis[1,2-bis(4-methoxyphenyl)-1,2-ethenedithiolato(2-)-κS¹,κS²]nickel
• 1,2-Ethenedithiol, 1,2-bis(4-methoxyphenyl)-, nickel complex, (Z)-
• 1,2-ethenebis(thiolate), 1,2-bis(4-methoxyphenyl)-, (Z)-, nickel salt
• Ads 920Mc
• B 4360
• Bis(4,4'-dimethoxy-alpha,alpha'-stilbenedithiolato(2-))nickel
• Bis[1,2-di(p-methoxyphenyl)-1,2-ethylenedithiolato]nickel
• Nickel, bis(1,2-bis(4-methoxyphenyl)-1,2-ethenedithiolato(2-)-kappaS,kappaS')-, (SP-4-1)-
• Nickel, bis(1,2-bis(4-methoxyphenyl)-1,2-ethenedithiolato(2-)-kappaS1,kappaS2)-, (SP-4-1)-
• Nickel, bis[1,2-bis(4-methoxyphenyl)-1,2-ethenedithiolato(2-)-S,S′]-, (SP-4-1)-
• Nickel, bis[1,2-bis(4-methoxyphenyl)-1,2-ethenedithiolato(2-)-κS,κS′]-, (SP-4-1)-
• Nickel, bis[1,2-bis(4-methoxyphenyl)-1,2-ethenedithiolato(2-)-κS¹,κS²]-, (SP-4-1)-
• Nickel, bis[4,4′-dimethoxy-α,α′-stilbenedithiolato(2-)]-

Bis[4,4'-dimethoxy(dithiobenzil)]nickel(II)

CAS: 38951-97-2

Formula: C₃₂H₂₈NiO₄S₄

Purity: >98.0%(HPLC)

Color and Shape: Black powder to crystal

Molecular weight: 663.51

Ref: 3B-B4360

Bis[4,4'-dimethoxy(dithiobenzil)]nickel(II)

CAS: 38951-97-2

Bis[4,4'-dimethoxy(dithiobenzil)]nickel(II)

Purity: >98.0%

Ref: 54-IN13186

bis[4,4'-dimethoxy-α,α'-stilbenedithiolato(2-)]nickel

CAS: 38951-97-2

Formula: C₃₂H₂₈NiO₄S₄

Purity: 98%

Color and Shape: Solid

Molecular weight: 663.5157

Ref: IN-DA00C9ZC