CAS 4039-32-1: Lithium bis(trimethylsilyl)amide

Description:Lithium bis(trimethylsilyl)amide, with the CAS number 4039-32-1, is an organolithium compound characterized by its strong basicity and nucleophilicity. It features a lithium cation coordinated to a bis(trimethylsilyl)amide anion, which consists of two trimethylsilyl groups attached to a nitrogen atom. This compound is typically a white to light yellow solid and is highly soluble in non-polar solvents such as hexane and toluene, making it useful in various organic synthesis applications. Its strong basic properties allow it to deprotonate a wide range of substrates, facilitating reactions such as the formation of carbon-carbon bonds. Additionally, lithium bis(trimethylsilyl)amide is often employed as a reagent in the synthesis of complex organic molecules and in the preparation of lithium-containing intermediates. However, it should be handled with care due to its reactivity and potential to react with moisture, which can lead to the release of flammable gases. Overall, this compound is a valuable tool in synthetic organic chemistry and materials science.

Formula:C₆H₁₉NSi₂·Li

InChI:InChI=1S/C6H19NSi2.Li/c1-8(2,3)7-9(4,5)6;/h7H,1-6H3;

InChI key:InChIKey=QQIRAVWVGBTHMJ-UHFFFAOYSA-N

SMILES:[Li].N([Si](C)(C)C)[Si](C)(C)C

Synonyms:
(Hexamethyldisilazane)lithium
1,1,1,3,3,3-Hexamethyldisilazane Lithium Salt
1,1,1-Trimethyl-N-(trimethylsilyl)silanamine lithium salt
Bis(trimethylsilyl)amide de lithium
Bis(trimethylsilyl)amidolithium
Disilazane, 1,1,1,3,3,3-hexamethyl-, Li deriv.
Disilazane, 1,1,1,3,3,3-hexamethyl-, lithium salt
Hexamethyldisilazane lithium salt
Hexamethyldisilazide, Lithium
Lhmds
See more synonyms
LiHMDS
Lithiobis(trimethylsilyl)amide
Lithiohexamethyldisilazane
Lithium bis(trimethylsilyl)amide
Lithium bis(trimethylsilyl)amide(1-)
Lithium bis(trimethylsilyl)amine
Lithium hexamethyldisilazanate
Lithium hexamethyldisilazane
Lithium hexamethyldisilazanide
Lithium hexamethyldisilazide
Lithium, [bis(trimethylsilyl)amino]-
Lithiumbis(Trimethylsilyl)Amide
Lithiumbis(trimethylsilyl)amid
Litiobis(Trimetilsilil)Amida
N,N-Bis(trimethylsilyl)amine lithium salt
N-Lithiohexamethyldisilazane
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, lithium salt (1:1)
[1,1,1-Trimethyl-N-(trimethylsilyl)silanaminato]lithium
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, lithium salt
lithium 1,1,1,3,3,3-hexamethyldisilazan-2-ide

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products per page. Found 20 products.

Product data	Purity	Price range	Estimated delivery
Lithium bis(trimethylsilyl)amide, 20% (ca 1.06M) soln. in THF/ethylbenzene, packaged in resealable septum cap bottle REF: 02-L15012CAS: 4039-32-1	- - -	96.00 €~346.00 €	Mon 07 Apr 25
Lithium bis(trimethylsilyl)amide, 0.9-1.1M in hexane, packaged under Argon in resealable ChemSeal™ bottles REF: 02-041872CAS: 4039-32-1	- - -	To inquire	Mon 07 Apr 25
CALLERY™ Lithium hexamethyldisilazane, 24% solution in tetrahydrofuran REF: 08-03-1275CAS: 4039-32-1	- - -	104.00 €~594.00 €	Tue 08 Apr 25
Hexamethyldisilazane lithium salt 1M in THF REF: 10-S09630CAS: 4039-32-1	- - -	37.00 €~189.00 €	Wed 09 Apr 25
Lithium bis(trimethylsilyl)amide REF: IN-DA0037VGCAS: 4039-32-1	- - -	To inquire	Tue 15 Apr 25
Lithium bis(trimethylsilyl)amide, 1M in Toluene REF: 54-OR55129CAS: 4039-32-1	- - -	To inquire	Mon 14 Apr 25
Lithium bis(trimethylsilyl)amide, 24% (1.4M) in THF REF: 54-OR54832CAS: 4039-32-1	- - -	To inquire	Mon 14 Apr 25
Lithium Bis(trimethylsilyl)amide (ca. 26% in Tetrahydrofuran, ca. 1.3mol/L) REF: 3B-H0915CAS: 4039-32-1	- - -	66.00 €~210.00 €	Wed 16 Apr 25
Lithium bis(trimethylsilyl)amide, 1M solution in THF/Ethylbenzene, AcroSeal™ REF: AC-34770CAS: 100-41-4 109-99-9 4039-32-1	- - -	To inquire	Wed 16 Apr 25
Lithium bis(trimethylsilyl)amide, 1M solution in THF, AcroSeal™ REF: AC-20955CAS: 109-99-9 4039-32-1	- - -	61.00 €~262.00 €	Wed 16 Apr 25
Lithium bis(trimethylsilyl)amide, 95% REF: AC-33814CAS: 4039-32-1	95%	37.00 €~402.00 €	Wed 16 Apr 25
Lithium bis(trimethylsilyl)amide, 1.0M sol. in methyl tert-butyl ether, AcroSeal™ REF: AC-34567CAS: 1634-04-4 4039-32-1	- - -	To inquire	Wed 16 Apr 25
Lithium bis(trimethylsilyl)amide, 1M in THF/2-methyl-2-butene REF: 54-OR460028CAS: 4039-32-1	- - -	118.00 €~486.00 €	Tue 22 Apr 25
LITHIUM HEXAMETHYLDISILAZIDE 1M in tetrahydrofuran REF: 3H-SIL6467.4CAS: 4039-32-1	- - -	To inquire	Mon 28 Apr 25
LITHIUM HEXAMETHYLDISILAZIDE, 95% REF: 3H-SIL6467.0CAS: 4039-32-1	95%	- - -	Discontinued product
LITHIUM HEXAMETHYLDISILAZIDE, 0.85M in hexane (19-21 wt %) REF: 3H-SIL6467.2CAS: 4039-32-1	- - -	- - -	Discontinued product
Lithium bis(trimethylsilyl)amide - 1.4 M in THF REF: 3D-FL165131CAS: 4039-32-1	Min. 95%	- - -	Discontinued product
Lithium bis(trimethylsilyl)amide - solution 1.0 M in MTBE REF: 3D-FL165181CAS: 4039-32-1	Min. 95%	- - -	Discontinued product
Lithium bis(trimethylsilyl)amide ,1.0 M in THF solution REF: 3D-FL181896CAS: 4039-32-1	Min. 95%	- - -	Discontinued product
Lithium hexamethyl disilazide solution - 1 M in tert-butyl methyl ether REF: 3D-FL146829CAS: 4039-32-1	Min. 95%	- - -	Discontinued product