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CAS 41536-18-9

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[1,2-Bis(diphenyphosphino)ethane]dichloroiron(II)

Description:
[1,2-Bis(diphenylphosphino)ethane]dichloroiron(II), commonly referred to as Fe(dppf)Cl2, is a coordination compound featuring an iron center coordinated to two chloride ions and a bidentate ligand, 1,2-bis(diphenylphosphino)ethane (dppf). This compound typically exhibits a square planar geometry around the iron(II) center, which is characteristic of d8 metal complexes. The dppf ligand, with its two phosphine groups, provides strong σ-donor and π-acceptor properties, enhancing the stability and reactivity of the complex. It is often used as a catalyst in various organic reactions, including cross-coupling reactions, due to its ability to facilitate the transfer of electrons. The compound is generally soluble in organic solvents, making it suitable for use in synthetic chemistry. Additionally, its properties can be influenced by the presence of other ligands or reaction conditions, allowing for versatility in catalytic applications. Safety precautions should be taken when handling this compound, as it may pose health risks if ingested or inhaled.
Formula:C26H24Cl2FeP2
InChI:InChI=1/C26H24P2.2ClH.Fe/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
SMILES:c1ccc(cc1)P(CCP(c1ccccc1)c1ccccc1)c1ccccc1.Cl.Cl.[Fe]
Synonyms:
  • (1,2-bis(diphenylphosphino)ethane)-dichloroiron(I)
  • Dichloroiron-Ethane-1,2-Diylbis(Diphenylphosphane)(1:1)
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