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CAS 43077-29-8

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(S)-(+)-Neomenthyldiphenylphosphine (S)-NMDPP

Description:
(S)-(+)-Neomenthyldiphenylphosphine, commonly referred to as (S)-NMDPP, is a chiral organophosphorus compound characterized by its unique structure that includes a phosphine group attached to a neomenthyl moiety and two phenyl groups. This compound is notable for its application in asymmetric synthesis and catalysis, particularly in reactions that require chiral ligands. The presence of the neomenthyl group imparts steric hindrance, which can influence the reactivity and selectivity of the compound in various chemical reactions. (S)-NMDPP is typically a solid at room temperature and exhibits good solubility in organic solvents. Its chirality is significant in the context of enantioselective processes, making it a valuable tool in the synthesis of enantiomerically pure compounds. Additionally, the compound's stability and reactivity can be influenced by the electronic properties of the phenyl groups, which can participate in coordination with metal centers in catalytic applications. Overall, (S)-NMDPP is an important compound in the field of organophosphorus chemistry and asymmetric synthesis.
Formula:C22H29P
InChI:InChI=1/C22H29P/c1-17(2)21-15-14-18(3)16-22(21)23(19-10-6-4-7-11-19)20-12-8-5-9-13-20/h4-13,17-18,21-22H,14-16H2,1-3H3/t18-,21+,22+/m1/s1
Synonyms:
  • (S)-(+)-Neomenthyldiphenylphosphine
  • (S)-Nmdpp
  • [(1S,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl](diphenyl)phosphane
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