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CAS 442905-33-1

:

(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine

Description:
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine is a chiral ligand commonly used in coordination chemistry and catalysis. This compound features a bipyridine backbone, which is a common structural motif in coordination complexes, providing a platform for metal binding. The presence of multiple methoxy groups enhances its solubility and may influence its electronic properties, while the di(3,5-xylyl)phosphino substituents contribute to its steric and electronic characteristics, making it a potent ligand for transition metals. The chirality of the compound is significant, as it can lead to enantioselective reactions in catalysis, allowing for the synthesis of specific stereoisomers in chemical reactions. Its unique structure and properties make it valuable in asymmetric synthesis and in the development of new catalytic systems. Overall, this compound exemplifies the intricate design of ligands in modern chemistry, where modifications can lead to enhanced reactivity and selectivity in various chemical processes.
Formula:C46H50N2O4P2
InChI:InChI=1/C46H50N2O4P2/c1-27-13-28(2)18-35(17-27)53(36-19-29(3)14-30(4)20-36)39-25-41(49-9)47-45(51-11)43(39)44-40(26-42(50-10)48-46(44)52-12)54(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38/h13-26H,1-12H3
SMILES:Cc1cc(C)cc(c1)P(c1cc(C)cc(C)c1)c1cc(nc(c1c1c(cc(nc1OC)OC)P(c1cc(C)cc(C)c1)c1cc(C)cc(C)c1)OC)OC
Synonyms:
  • 4,4'-Bis[Bis(3,5-Dimethylphenyl)Phosphanyl]-2,2',6,6'-Tetramethoxy-3,3'-Bipyridine
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