CAS 52522-40-4

Palladium, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]di-, compd. with trichloromethane (1:1)

Description:

Palladium, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]di-, compd. with trichloromethane (1:1) is a coordination compound featuring palladium as the central metal ion coordinated to a specific ligand derived from a diphenyl-pentadienone structure. The compound exhibits characteristics typical of palladium complexes, including potential catalytic activity, particularly in organic transformations. The presence of the trichloromethane solvent indicates that the compound may be soluble in organic solvents, which is common for many metal-organic complexes. The ligands in this compound are likely to impart unique electronic and steric properties, influencing its reactivity and stability. Additionally, the compound may exhibit interesting optical properties due to the conjugated system present in the ligands. As with many palladium complexes, it may be of interest in fields such as catalysis, materials science, and organic synthesis, where palladium is often utilized for its ability to facilitate various chemical reactions. Safety and handling precautions should be observed due to the potential toxicity of both palladium compounds and trichloromethane.

Formula: C₅₁H₄₂O₃Pd₂·CHCl₃

InChI: InChI=1S/3C17H14O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;2-1(3)4;;/h3*1-14H;1H;;

InChI key: InChIKey=LNAMMBFJMYMQTO-UHFFFAOYSA-N

SMILES: O=C1[CH]=2[Pd]345([CH](=[CH]3C6=CC=CC=C6)C(=O)[CH]=7[Pd]89([CH]1=[CH]8C%10=CC=CC=C%10)([CH](C(=O)[CH]4=[CH]5C%11=CC=CC=C%11)=[CH]9C%12=CC=CC=C%12)[CH]7C%13=CC=CC=C%13)[CH]2C%14=CC=CC=C%14.C(Cl)(Cl)Cl

Synonyms:

• 1,2,4,5-Pentanetetrayl, 3-Oxo-1,5-Diphenyl-, Compd. With Trichloromethane, Palladium Salt (3:1:2)
• 1,4-Pentadien-3-one, 1,5-diphenyl-, palladium complex, (E,E)-
• Dipalladium(0)tris(dibenzylideneacetone)-chloroform adduct
• Dipalladiumtris(dibenzylideneacetone) chloroform adduct
• Methane, trichloro-, compd. with (all-E)-tris[μ-[(1,2-η:4,5-η)-1,5-diphenyl-1,4-pentadien-3-one]]dipalladium (1:1)
• Methane, trichloro-, compd. with tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]dipalladium (1:1)
• Palladium, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]di-, compd. with trichloromethane (1:1)
• Palladium, tris[μ-[(1,2-η:4,5-η)-1,5-diphenyl-1,4-pentadien-3-one]]di-, (all-E)-, compd. with trichloromethane (1:1)
• Pd₂(dba)₃.CHCl₃
• Tris(dibenzylideneacetone)dipalladium chloroform
• Tris(dibenzylideneacetone)dipalladium-chloroform (1:1)
• Tris(dibenzylideneacetone)dipalladium-chloroform adduct

Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6%

CAS: 52522-40-4

Tris(dibenzylideneacetone)dipalladium(0) is used in Synthesis of nanosized palladium phosphides upon interaction with white phosphorous, Preparation of palladium triphenylphosphine carbonyl cluster complexes, Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes

Formula: C₅₂H₄₃Cl₃O₃Pd₂

Molecular weight: 1035.10

Ref: 02-044969

Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct

CAS: 52522-40-4

Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct

Formula: (C₆H₅CHCHCOCHCHC₆H₅)₃Pd₂·CHCl₃

Color and Shape: red to brown solid

Molecular weight: 1035.08

Ref: 08-46-3010

Tris(dibenylideneacetone)dipalladium-chloroform

CAS: 52522-40-4

Formula: C₅₂H₄₃Cl₃O₃Pd₂

Purity: 98%

Color and Shape: Solid

Molecular weight: 1035.0950

Ref: IN-DA003V7X

Tris(dibenzylideneacetone)dipalladium chloroform adduct

CAS: 52522-40-4

Tris(dibenzylideneacetone)dipalladium chloroform adduct

Purity: 98%

Color and Shape: Dark Brown Black Powder

Molecular weight: 1,035.10g/mol

Ref: 54-IN2825

Tris(dibenzylideneacetone)dipalladium(0)-chloroform Adduct

Controlled Product

CAS: 52522-40-4

Formula: C₅₂H₄₃Cl₃O₃Pd₂

Color and Shape: Neat

Molecular weight: 1035.1

Ref: TR-T876350

Tris(Dibenzylideneacetone)dipalladium (0)chloroform adduct

CAS: 52522-40-4

Formula: C₅₂H₄₃Cl₃O₃Pd₂

Purity: 98%

Color and Shape: Solid

Molecular weight: 1035.1

Ref: 10-F035788

Tris(dibenzylideneacetone)dipalladium (0)-chloroform adduct

Controlled Product

CAS: 52522-40-4

Tris(dibenzylideneacetone)dipalladium (0)-chloroform adduct is a catalyst that is used in cross-coupling reactions. It is an efficient method for the preparation of β-unsaturated ketones, which are important intermediates in organic synthesis. The catalytic cycle involves hydrolysis and condensation reactions. Tris(dibenzylideneacetone)dipalladium (0)-chloroform adduct can be prepared by reacting chloroform with a palladium compound in the presence of silver trifluoromethanesulfonate and a diphosphine ligand. The product contains a chloroform molecule that can be replaced by other functional groups such as chloride, fatty acid, or imine nitrogen. Tris(dibenzylideneacetone)dipalladium (0)-chloroform adduct has been characterized by x-ray crystal structures to identify

Formula: C₅₁H₄₂O₃Pd₂·CHCl₃

Purity: Min. 95%

Color and Shape: Powder

Molecular weight: 1,035.09 g/mol

Ref: 3D-FT48252

Tris(Dibenzylideneacetone)Dipalladium-Chloroform Adduct extrapure, 20% Pd

CAS: 52522-40-4

Formula: C₅₂H₄₃Cl₃O₃Pd

Color and Shape: Purple to black, Crystalline powder

Molecular weight: 1035.1

Ref: SR-96455