CAS 528565-84-6

Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-ethanediyl)bis[2,5-diphenylphospholane-κP]]-, tetrafluoroborate(1-) (1:1)

Description:

Rhodium(1+), with the specified complex structure, is a coordination compound featuring rhodium in a +1 oxidation state. This compound is characterized by its unique ligand environment, which includes a cyclooctadiene and a bisphosphine ligand, specifically 1,1′-(1,2-ethanediyl)bis[2,5-diphenylphospholane]. The presence of the tetrafluoroborate counterion indicates that it is a salt, contributing to its solubility and stability in various solvents. The complex exhibits interesting electronic properties due to the coordination of the phosphine ligands, which can influence its reactivity and catalytic behavior. Rhodium complexes are often utilized in catalysis, particularly in organic synthesis and hydrogenation reactions, due to their ability to facilitate electron transfer processes. The specific stereochemistry of the ligands can also impart unique properties, affecting the compound's reactivity and selectivity in chemical reactions. Overall, this rhodium complex represents a sophisticated example of organometallic chemistry, showcasing the interplay between metal centers and organic ligands.

Formula: C₄₂H₄₈BF₄P₂Rh

InChI: InChI=1S/C34H36P2.C8H12.BF4.Rh/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-20,31-34H,21-26H2;1-2,7-8H,3-6H2;;/q;;-1;+1/t31-,32-,33-,34-;;;/m1.../s1

InChI key: InChIKey=HOYBXERAQSXVFT-XQOBNKNKSA-N

SMILES: [Rh+]1234([P]5([C@H](CC[C@@H]5C6=CC=CC=C6)C7=CC=CC=C7)CC[P]18[C@H](CC[C@@H]8C9=CC=CC=C9)C%10=CC=CC=C%10)[CH]%11=[CH]2CC[CH]3=[CH]4CC%11.[B+3]([F-])([F-])([F-])[F-]

Synonyms:

• Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-ethanediyl)bis[2,5-diphenylphospholane-κP]]-, tetrafluoroborate(1-) (1:1)
• Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-ethanediyl)bis[2,5-diphenylphospholane-κP]]-, tetrafluoroborate(1-)
• (R,R)-PH-BPE-RH
• (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-Ph-BPE-Rh
• (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

1,2-Bis[(2R,5R)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate

CAS: 528565-84-6

Formula: C₄₂H₄₈BF₄P₂Rh

Purity: 98%

Color and Shape: Solid

Molecular weight: 804.4882

Ref: IN-DA003DCY

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

CAS: 528565-84-6

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Purity: 98%

Molecular weight: 804.49g/mol

Ref: 54-IN11781

(-)-1,2-Bis((2R,5R)-2,5-diphenyl­phospholano)ethane(1,5-cyclo­octadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh

CAS: 528565-84-6

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh

Formula: Rh(C₈H₁₂)(C₃₄H₃₆P₂)BF₄

Purity: min. 98%

Color and Shape: orange xtl.

Molecular weight: 804.49

Ref: 08-45-0201

1,​2-​Bis[(2R,​5R)​-​2,​5-​diphenylphospholano]​ethane(1,​5-​cyclooctadiene)​rhodium(I) Tetrafluoroborate

Controlled Product

CAS: 528565-84-6

Formula: C₄₂H₄₈P₂Rh•BF₄

Color and Shape: Neat

Ref: TR-B016045