CAS 5450-26-0

α-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-, 3-methanesulfonate

Description:

α-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-, 3-methanesulfonate is a chemical compound that belongs to the class of glycosides, specifically a derivative of glucose. This compound features a furanose form of glucose, which is characterized by a five-membered ring structure. The presence of methanesulfonate as a substituent indicates that it has a sulfonate group, which can enhance its solubility in polar solvents and may also influence its reactivity. The bis-O-(1-methylethylidene) groups suggest that the compound has protective groups that can stabilize the sugar moiety and prevent unwanted reactions. This compound is typically used in organic synthesis and may serve as an intermediate in the preparation of more complex carbohydrates or glycosylated compounds. Its unique structure allows for specific interactions in biochemical applications, making it of interest in both synthetic and medicinal chemistry. As with many chemical substances, proper handling and safety precautions should be observed due to potential reactivity and toxicity associated with sulfonate groups.

Formula: C₁₃H₂₂O₈S

InChI: InChI=1S/C13H22O8S/c1-12(2)16-6-7(18-12)8-9(21-22(5,14)15)10-11(17-8)20-13(3,4)19-10/h7-11H,6H2,1-5H3/t7-,8-,9+,10-,11-/m1/s1

InChI key: InChIKey=CLCAOXSGSHWACR-KAMPLNKDSA-N

SMILES: O(S(C)(=O)=O)[C@H]1[C@](O[C@]2([C@@]1(OC(C)(C)O2)[H])[H])([C@]3(COC(C)(C)O3)[H])[H]

Synonyms:

• (3aR,5R,6S,6aR)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-yl methanesulfonate (non-preferred name)
• 1,2:5,6-Di-O-Isopropylidene-3-O-(Methylsulfonyl)-Alpha-D-Glucofuranose
• 1,2:5,6-Di-O-isopropylidene-3-O-mesyl-α-<span class="text-smallcaps">D</span>-glucofuranose
• 3-O-(Methylsulfonyl)-1,2;5,6-di-O-isopropylidene-α-<span class="text-smallcaps">D</span>-glucofuranose
• 3-O-Methylsulphonyl-1,2,5,6-di-O-isopropylidene-alpha-D-glucofuranose
• 5-(2,2-Dimethyl-1,3-Dioxolan-4-Yl)-2,2-Dimethyltetrahydrofuro[2,3-D][1,3]Dioxol-6-Yl Methanesulfonate (Non-Preferred Name)
• Ai3-61546
• D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-, 3-methanesulfonate
• Furo[2,3-d]-1,3-dioxole, α-<span class="text-smallcaps">D</span>-glucofuranose deriv.
• Glucofuranose, 1,2:5,6-di-O-isopropylidene-, methanesulfonate, α-<span class="text-smallcaps">D</span>-
• [(3aR,5R,6S,6aR)-5-(2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[4,5-d][1,3]dioxol-6-yl] methanesulfonate
• α-<span class="text-smallcaps">D</span>-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-, 3-methanesulfonate
• α-<span class="text-smallcaps">D</span>-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-, methanesulfonate
• α-<span class="text-smallcaps">D</span>-Glucofuranose, 1,2:5,6-di-O-isopropylidene-, 3-methanesulfonate
• Glucofuranose, 1,2:5,6-di-O-isopropylidene-, methanesulfonate, α-D-
• Furo[2,3-d]-1,3-dioxole, α-D-glucofuranose deriv.
• α-D-Glucofuranose, 1,2:5,6-di-O-isopropylidene-, 3-methanesulfonate
• α-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-, methanesulfonate

1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-a-D-glucofuranose

CAS: 5450-26-0

Ref: 7W-GC4659

1,2:5,6-Di-O-isopropylidene-3-O-methanesulfonyl-α-D-glucofuranose

CAS: 5450-26-0

A protected glucofuranose.

Formula: C₁₃H₂₂O₈S

Purity: Min. 95%

Color and Shape: White To Off-White Solid

Molecular weight: 338.37 g/mol

Ref: 3D-MD06143