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CAS 55266-18-7

:

Manganate(4-), chloro[[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl-κN21,κN22,κN23,κN24)tetrakis[benzoato]](6-)]-, hydrogen (1:4), (SP-5-12)-

Description:
The chemical substance known as Manganate(4-), chloro[[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl-κN21,κN22,κN23,κN24)tetrakis[benzoato]](6-)]-, hydrogen (1:4), (SP-5-12)-, with the CAS number 55266-18-7, is a complex coordination compound featuring a manganese center coordinated to a porphyrin derivative. This substance exhibits characteristics typical of metalloporphyrins, including a robust chromophore that can absorb visible light, making it useful in various applications such as catalysis and photodynamic therapy. The presence of benzoate ligands contributes to its stability and solubility in organic solvents. The manganese in the manganate form typically exhibits oxidation states that can participate in redox reactions, which is significant for its reactivity and potential applications in electrochemistry. Additionally, the chloro substituent may influence the electronic properties and coordination behavior of the complex. Overall, this compound represents a fascinating intersection of organic and inorganic chemistry, with potential implications in materials science and biochemistry.
Formula:C48H24ClMnN4O8·4H
InChI:InChI=1S/C48H30N4O8.ClH.Mn/c53-45(54)29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(12-4-26)46(55)56)37-21-23-39(51-37)44(28-7-15-32(16-8-28)48(59)60)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(14-6-27)47(57)58;;/h1-24H,(H6,49,50,51,52,53,54,55,56,57,58,59,60);1H;/q;;+3/p-3/b41-33-,41-34?,42-35-,42-37?,43-36-,43-38?,44-39-,44-40?;;
InChI key:InChIKey=XHVDAQLNUQLQKW-PTJHDCLZSA-K
SMILES:[Cl-][Mn+3]123[N-]4C5=C(C6=[N]1C(=C(C=7[N-]2C(C(=C8[N]3=C(C(=C4C=C5)C9=CC=C(C([O-])=O)C=C9)C=C8)C%10=CC=C(C([O-])=O)C=C%10)=CC7)C%11=CC=C(C([O-])=O)C=C%11)C=C6)C%12=CC=C(C([O-])=O)C=C%12.[H+]
Synonyms:
  • Manganate(4-), chloro[[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis[benzoato]](6-)-N21,N22,N23,N24]-, tetrahydrogen, (SP-5-12)-
  • Manganate(4-), chloro[[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl-κN21,κN22,κN23,κN24)tetrakis[benzoato]](6-)]-, hydrogen (1:4), (SP-5-12)-
  • [5,10,15,20-Tetrakis(4-carboxyphenyl)-21H,23H-porphine]manganese(III) chloride
  • Benzoic acid, 4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, manganese complex
  • Manganate(4-), chloro[[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl-κN21,κN22,κN23,κN24)tetrakis[benzoato]](6-)]-, tetrahydrogen, (SP-5-12)-
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