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CAS 55650-59-4

:

(2S)-1-[(1S)-1-(Dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)ferrocene

Description:
The chemical substance known as (2S)-1-[(1S)-1-(Dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)ferrocene, with the CAS number 55650-59-4, is a chiral organometallic compound that features a ferrocene core, which is a metallocene consisting of an iron atom sandwiched between two cyclopentadienyl anions. This compound is characterized by its unique structure that includes two diphenylphosphino groups, which are known for their ability to act as ligands in coordination chemistry. The presence of the dimethylaminoethyl substituent contributes to its solubility and reactivity, making it useful in various catalytic applications, particularly in asymmetric synthesis. The chirality of the compound is significant, as it can influence the selectivity and efficiency of reactions in which it participates. Additionally, the phosphine ligands can stabilize metal complexes, enhancing their catalytic properties. Overall, this compound exemplifies the intersection of organometallic chemistry and asymmetric catalysis, showcasing the importance of structural features in determining chemical behavior.
Formula:C38H37FeNP2
InChI:InChI=1S/C21H23NP.C17H14P.Fe/c1-17(22(2)3)20-15-10-16-21(20)23(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h4-17H,1-3H3;1-14H;/q2*-1;+2
InChI key:InChIKey=IEEIDZAXDTVGGN-UHFFFAOYSA-N
SMILES:P(C1=2[Fe+2]3456789([C-]1(C(N(C)C)C)[CH]3=[CH]4[CH]52)[C-]%10(P(C%11=CC=CC=C%11)C%12=CC=CC=C%12)[CH]6=[CH]7[CH]8=[CH]9%10)(C%13=CC=CC=C%13)C%14=CC=CC=C%14
Synonyms:
  • (2S)-1-[(1S)-1-(Dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)ferrocene
  • (S)-N,N-Dimethyl-1-[(R)-1,2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • (S,R)-1-(1-dimethylaminoethyl)-1,2-*bis(diphenyl
  • 1,2,3,4,5-cyclopentanepentayl, 1-[(1S)-1-(dimethylamino)ethyl]-2-(diphenylphosphino)-, compd. with 1-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
  • Ferrocene, 1-[(1S)-1-(dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)-, (2S)-
  • Ferrocene, 1-[1-(dimethylamino)ethyl]-1′,2-bis(diphenylphosphino)-, [S-(R*,R*)]-
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