CAS 60804-75-3: Ruthenium(2+), tris(1,10-phenanthroline-κN1,κN10)-, (OC-6-11)-, hexafluorophosphate(1-) (1:2)
Description:Ruthenium(2+), tris(1,10-phenanthroline-κN1,κN10)-, (OC-6-11)-, hexafluorophosphate(1-) is a coordination complex featuring ruthenium as the central metal ion, coordinated to three 1,10-phenanthroline ligands. This complex exhibits a +2 oxidation state for ruthenium, which is common in transition metal complexes, particularly those involving d6 electron configurations. The 1,10-phenanthroline ligands are bidentate, coordinating through nitrogen atoms, and contribute to the stability and electronic properties of the complex. The hexafluorophosphate counterion (PF6-) is a common choice in coordination chemistry, providing a stable and non-coordinating anion that helps to balance the charge of the complex. This compound is often studied for its photophysical properties, potential applications in photochemistry, and as a catalyst in various chemical reactions. Its solubility and reactivity can be influenced by the presence of the hexafluorophosphate anion, making it a subject of interest in both academic and industrial research.
Formula:C36H24N6Ru·2F6P
InChI:InChI=1S/3C12H8N2.F6P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;1-7(2,3,4,5)6;/h3*1-8H;;/q;;;-1;+2
InChI key:InChIKey=KJAHFQMMYKXRNO-UHFFFAOYSA-N
SMILES:[F-][P+5]([F-])([F-])([F-])([F-])[F-].C=1C=C2C=CC3=CC=C[N]4=C3C2=[N](C1)[Ru+2]456([N]=7C=CC=C8C=CC9=CC=C[N]5=C9C87)[N]=%10C=CC=C%11C=CC%12=CC=C[N]6=C%12C%11%10
- Synonyms:
- Tris(1,10-phenanthroline)ruthenium bis(hexafluorophosphate(1-))
- Phosphate(1-), hexafluoro-, (OC-6-11)-tris(1,10-phenanthroline-N1,N10)ruthenium(2+) (2:1)
- Ruthenium(2+), tris(1,10-phenanthroline-N1,N10)-, (OC-6-11)-, bis[hexafluorophosphate(1-)]
- Ruthenium(2+), tris(1,10-phenanthroline-κN1,κN10)-, (OC-6-11)-, bis[hexafluorophosphate(1-)]
- Ruthenium(2+), tris(1,10-phenanthroline-κN1,κN10)-, (OC-6-11)-, hexafluorophosphate(1-) (1:2)
