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CAS 60804-75-3

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Ruthenium(2+), tris(1,10-phenanthroline-κN1,κN10)-, (OC-6-11)-, hexafluorophosphate(1-) (1:2)

Description:
Ruthenium(2+), tris(1,10-phenanthroline-κN1,κN10)-, (OC-6-11)-, hexafluorophosphate(1-) is a coordination complex featuring ruthenium as the central metal ion, coordinated to three 1,10-phenanthroline ligands. This complex exhibits a +2 oxidation state for ruthenium, which is common in transition metal complexes, particularly those involving d6 electron configurations. The 1,10-phenanthroline ligands are bidentate, coordinating through nitrogen atoms, and contribute to the stability and electronic properties of the complex. The hexafluorophosphate counterion (PF6-) is a common choice in coordination chemistry, providing a stable and non-coordinating anion that helps to balance the charge of the complex. This compound is often studied for its photophysical properties, potential applications in photochemistry, and as a catalyst in various chemical reactions. Its solubility and reactivity can be influenced by the presence of the hexafluorophosphate anion, making it a subject of interest in both academic and industrial research.
Formula:C36H24N6Ru·2F6P
InChI:InChI=1S/3C12H8N2.F6P.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;1-7(2,3,4,5)6;/h3*1-8H;;/q;;;-1;+2
InChI key:InChIKey=KJAHFQMMYKXRNO-UHFFFAOYSA-N
SMILES:[Ru+2]123([N]=4C=5C=6[N]1=CC=CC6C=CC5C=CC4)([N]=7C=8C=9[N]2=CC=CC9C=CC8C=CC7)[N]=%10C=%11C=%12[N]3=CC=CC%12C=CC%11C=CC%10.[P+5]([F-])([F-])([F-])([F-])([F-])[F-]
Synonyms:
  • Tris(1,10-phenanthroline)ruthenium bis(hexafluorophosphate(1-))
  • Phosphate(1-), hexafluoro-, (OC-6-11)-tris(1,10-phenanthroline-N1,N10)ruthenium(2+) (2:1)
  • Ruthenium(2+), tris(1,10-phenanthroline-N1,N10)-, (OC-6-11)-, bis[hexafluorophosphate(1-)]
  • Ruthenium(2+), tris(1,10-phenanthroline-κN1,κN10)-, (OC-6-11)-, bis[hexafluorophosphate(1-)]
  • Ruthenium(2+), tris(1,10-phenanthroline-κN1,κN10)-, (OC-6-11)-, hexafluorophosphate(1-) (1:2)
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