CAS 61717-82-6

1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide

Description:

1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide, commonly referred to as IBX (Iodoxybenzoic acid), is an organoiodine compound known for its utility as an oxidizing agent in organic synthesis. It features a benziodoxole structure, which includes a five-membered ring containing iodine and oxygen atoms. This compound is typically a white to off-white solid and is soluble in polar organic solvents. IBX is particularly valued for its ability to oxidize alcohols to carbonyl compounds, such as aldehydes and ketones, under mild conditions, making it a versatile reagent in synthetic organic chemistry. Its reactivity is attributed to the presence of the iodine atom, which can participate in various oxidation reactions. Additionally, IBX is relatively stable under standard conditions but should be handled with care due to its potential reactivity. Overall, its unique structure and properties make it a significant tool for chemists seeking efficient oxidation methods in their synthetic pathways.

Formula: C₇H₅IO₄

InChI: InChI=1/C7H5IO3/c8-11-6-4-2-1-3-5(6)7(9)10/h1-4H,(H,9,10)

InChI key: InChIKey=CQMJEZQEVXQEJB-UHFFFAOYSA-N

SMILES: O=I1(O)C=2C(C(=O)O1)=CC=CC2

Synonyms:

• 1,2-Benziodoxol-3(1H)-one, 1-hydroxy-, 1-oxide
• 1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide
• 1-Hydroxy-1,2-benziodoxole-3(1H)-one 1-oxide
• 1-Hydroxy-1,2-benziodoxy-3-(1h)-one-1-xoide
• 1-Hydroxy-1,3-dioxo-3H-benz[d][1,2]iodoxol
• 1-Hydroxy-3H-benz[d][1,2]iodoxol-1,3-dione
• 1-Hydroxyl-2-benziodoxol-3(1H)-one 1-oxide
• 1-hydroxy-1lambda~3~,2-benziodoxol-3(1H)-one 1-oxide
• 2-(Iodooxy)Benzoic Acid
• 2-Iodylbenzoic Acid
• IBX
• NSC 366248
• 1-HYDROXY-1,2-BENZIODOXOL-3(H)-ONE 1-OXIDE
• 2-IODOXYBENZOIC ACID, STABILIZED (45 WT&
• IbxO-IodoxybenzoicAcid
• 2-Iodoxybenzoic acid
• IBX(1-HYDROXY-1,2-BENZIODOXOL-3(1H)-ONE-1-OXIDE)
• SIBX, Stabilized IBX
• 2-Iodoxybenzoic acid, stabilized (45 wt.% IBX)
• 2-Iodoxybenzoic acid ,39-50% [Stabilizer：Benzoic acid 23%，Isophtalic acid 30%]

2-Iodoxybenzoic Acid (stabilized with Benzoic Acid + Isophthalic Acid)

CAS: 61717-82-6

Formula: C₇H₅IO₄

Purity: >39.0%(T)

Color and Shape: White to Almost white powder to crystal

Molecular weight: 280.02

Ref: 3B-I0791

1-hydroxy-1-oxo-3H-1λ5,2-benziodaoxol-3-one

CAS: 61717-82-6

Formula: C₇H₅IO₄

Purity: %

Color and Shape: Solid

Molecular weight: 280.0167

Ref: IN-DA0033DA

2-Iodoxybenzoic acid, 45 wt. % IBX

CAS: 61717-82-6

2-Iodoxybenzoic acid, 45 wt. % IBX

Formula: C₇H₅IO₄

Purity: ≥95%

Color and Shape: white crystalline solid

Molecular weight: 280.01667g/mol

Ref: 54-OR3108

2-Iodoxybenzoic Acid

Controlled Product

CAS: 61717-82-6

Applications 2-Iodoxybenzoic Acid is used in the oxidation of alcohols in organic synthesis. It is also frequently used in the preparation of Dess-Martin periodinane.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Frigerio, M. et al.: J. Org. Chem., 60, 7272 (1995); Ireland, R. et al.: J. Org. Chem., 58, 2899 (1993);

Formula: C₇H₅IO₄

Color and Shape: Neat

Molecular weight: 280.02

Ref: TR-I729400

2-Iodoxy benzoic acid

CAS: 61717-82-6

2-Iodoxybenzoic acid is an oxidizing agent that is used in photochemical reactions. It has been used to prepare aldehydes from amines and has been shown to have photocatalytic activity. 2-Iodoxybenzoic acid can be synthesized by dehydrogenation of the corresponding 2-iodoaniline with hydrochloric acid. The mechanism of this process is not well understood, but it may involve a free radical mechanism. Mechanistic studies indicate that 2-iodobenzoic acid may be a useful dehydrogenation agent or an oxidant in organic synthesis because it does not form hydrogen peroxide as a byproduct.

Formula: C₇H₅IO₄

Purity: Min. 95%

Color and Shape: Powder

Molecular weight: 280.02 g/mol

Ref: 3D-FI12584

2-Iodoxybenzoic acid (IBX) - 30% (contains stabiliser)

CAS: 61717-82-6

Formula: C₇H₅IO₄

Purity: 95.0%

Color and Shape: Solid

Molecular weight: 280.017

Ref: 10-F069184