CAS 619334-93-9

(R)-(-)-4,12-BIS(DI-3,5-XYLYLPHOSPHINO)[2.2]PARACYCLOPHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE

Description:

(R)-(-)-4,12-BIS(DI-3,5-XYLYLPHOSPHINO)[2.2]PARACYCLOPHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE is a complex organometallic compound that features a rhodium center coordinated with a unique ligand system. The compound is characterized by its chiral nature, attributed to the presence of the (R)-(-) configuration, which can influence its reactivity and selectivity in catalytic processes. The bis(dialkylphosphino) ligand provides strong donor properties, enhancing the stability of the rhodium center and facilitating its role in various catalytic applications, particularly in asymmetric synthesis. The tetrafluoroborate counterion contributes to the overall solubility and stability of the complex in various solvents. This compound is often utilized in homogeneous catalysis, especially in reactions such as hydrogenation and cross-coupling, where its chiral environment can lead to enantioselective outcomes. Its structural features, including the para-cyclophane framework, contribute to its unique electronic and steric properties, making it a valuable tool in synthetic organic chemistry.

Formula: C₄₈H₅₀P₂·C₈H₁₂·BF₄·HRh

Synonyms:

• (R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%
• (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)[2.2]paracyclophane(1,5-cyclooctadiene)
• (S)-(+)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
• rhodium(I) tetrafluoroborate, min. 97%
• (R)-(-)-4,12-BIS(DI-3,5-XYLYLPHOSPHINO)[2.2]PARACYCLOPHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
• (S)-(+)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%
• (S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)[2.2]paracyclophane(1,5-cyclooctadiene)
• (R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%

(R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%

CAS: 619334-93-9

(R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%

Formula: C₅₆H₆₂P₂RhBF₄

Purity: min. 97%

Color and Shape: yellow-orange xtl.

Molecular weight: 986.75

Ref: 08-45-0213