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CAS 63488-10-8

:

Bromo[4-(1,1-dimethylethyl)phenyl]magnesium

Description:
Bromo[4-(1,1-dimethylethyl)phenyl]magnesium, with the CAS number 63488-10-8, is an organomagnesium compound commonly classified as a Grignard reagent. This compound features a magnesium atom bonded to a bromo-substituted aromatic ring, specifically a para-substituted phenyl group with a bulky tert-butyl group (1,1-dimethylethyl) at the para position. Grignard reagents are known for their reactivity, particularly with electrophiles, making them valuable in organic synthesis for forming carbon-carbon bonds. The presence of the bromine atom enhances the reactivity of the compound, allowing it to participate in nucleophilic addition reactions. Additionally, the steric hindrance introduced by the tert-butyl group can influence the reactivity and selectivity of the reactions it undergoes. As with many Grignard reagents, it is sensitive to moisture and air, requiring an anhydrous environment for storage and use. Overall, Bromo[4-(1,1-dimethylethyl)phenyl]magnesium serves as a useful intermediate in the synthesis of various organic compounds.
Formula:C10H13BrMg
InChI:InChI=1/C10H13.BrH.Mg/c1-10(2,3)9-7-5-4-6-8-9;;/h5-8H,1-3H3;1H;/q;;+1/p-1/rC10H13BrMg/c1-10(2,3)8-4-6-9(12-11)7-5-8/h4-7H,1-3H3
InChI key:InChIKey=YECFWFOEQLAVNH-UHFFFAOYSA-M
SMILES:C(C)(C)(C)C1=CC=C([Mg]Br)C=C1
Synonyms:
  • (4-tert-Butylphenyl)magnesium bromide
  • (p-tert-Butylphenyl)magnesium bromide
  • 4-(1,1-Dimethylethyl)phenylmagnesium bromide
  • Benzene, (1,1-dimethylethyl)-, magnesium complex
  • Bromo(4-Tert-Butylphenyl)Magnesium
  • Bromo[4-(1,1-dimethylethyl)phenyl]magnesium
  • Magnesium, bromo(p-tert-butylphenyl)-
  • Magnesium, bromo[4-(1,1-dimethylethyl)phenyl]-
  • 4-tert-Butylphenylmagnesium bromide solution 0.5M in THF
  • 4-tert-ButylphenylMagnesiuM broMide, 0.5M solution in THF, J&KSeal
  • See more synonyms
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