CymitQuimica logo

CAS 64536-78-3

:

Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-, hexafluorophosphate(1-) (1:1)

Description:
Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-, hexafluorophosphate(1-) is a coordination complex featuring iridium in a +1 oxidation state. This compound is characterized by its unique ligand environment, which includes a cyclooctadiene moiety that contributes to its stability and reactivity. The presence of pyridine and tricyclohexylphosphine ligands enhances its solubility and may influence its electronic properties, making it suitable for various catalytic applications. The hexafluorophosphate counterion provides ionic stability and solubility in polar solvents. This complex is of interest in organometallic chemistry and catalysis, particularly in reactions involving C-H activation and other transformations. Its structural features allow for potential applications in organic synthesis and materials science, where iridium complexes are often utilized for their unique reactivity and ability to facilitate complex chemical transformations. Overall, this compound exemplifies the diverse chemistry of transition metal complexes and their utility in advanced chemical processes.
Formula:C31H50IrNP·F6P
InChI:InChI=1S/C18H33P.C8H12.C5H5N.F6P.Ir/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;1-2-4-6-5-3-1;1-7(2,3,4,5)6;/h16-18H,1-15H2;1-2,7-8H,3-6H2;1-5H;;/q;;;-1;+1
InChI key:InChIKey=UJXHUUQZACSUOG-UHFFFAOYSA-N
SMILES:[P]([Ir+]123([CH]4=[CH]1CC[CH]2=[CH]3CC4)[N]=5C=CC=CC5)(C6CCCCC6)(C7CCCCC7)C8CCCCC8.[P+5]([F-])([F-])([F-])([F-])([F-])[F-]
Synonyms:
  • (1,5-Cyclohexadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate
  • (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(1+) hexafluorophosphate
  • (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
  • (1,5-Cyclooctadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate
  • (1,5-cyclooctadiene)(pyrid.)(tric.hexyl-phosphine)irid(I)pf6
  • (Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate
  • (η<sup>4</sup>-1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate
  • 1,5-Cyclooctadiene, iridium complex
  • Crabtree'S Catalyst
  • Crabtrees Catalyst
  • See more synonyms
Sort by
Purity (%)
0
100
|
0
|
50
|
90
|
95
|
100
Found 7 products.