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CAS 649736-75-4

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Bis[1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κO]]dipalladium

Description:
Bis[1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κO]]dipalladium, with CAS number 649736-75-4, is a complex organometallic compound featuring palladium as the central metal. This compound is characterized by its unique ligand architecture, which includes bulky imidazolium-based ligands that enhance its stability and reactivity. The presence of naphthoquinone moieties contributes to its potential applications in catalysis, particularly in cross-coupling reactions and other organic transformations. The bulky substituents on the imidazolium ligands provide steric hindrance, which can influence the electronic properties and reactivity of the palladium center. Additionally, the compound's structure may exhibit interesting photophysical properties due to the naphthalenedione components. Overall, this compound represents a significant example of how ligand design can impact the behavior of transition metal complexes in various chemical processes.
Formula:C74H84N4O4Pd2
InChI:InChI=1S/2C27H36N2.2C10H6O2.2Pd/c2*1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;2*11-9-5-6-10(12)8-4-2-1-3-7(8)9;;/h2*9-16,18-21H,1-8H3;2*1-6H;;/q2*-2;;;2*+2
InChI key:InChIKey=SYABVQADSNYSBD-UHFFFAOYSA-N
SMILES:O=C1[CH]=2[Pd+2]3([CH]2C(=O[Pd+2]4([CH]=5C(=O3)C=6C(C(=O)[CH]54)=CC=CC6)=[C-2]7N(C=CN7C8=C(C(C)C)C=CC=C8C(C)C)C9=C(C(C)C)C=CC=C9C(C)C)C=%10C1=CC=CC%10)=[C-2]%11N(C=CN%11C%12=C(C(C)C)C=CC=C%12C(C)C)C%13=C(C(C)C)C=CC=C%13C(C)C
Synonyms:
  • Palladium, bis[1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κO]]di-
  • Bis[1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κO]]dipalladium
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