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CAS 67292-34-6

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[1,1'-Bis(diphenyphosphino)ferrocene]dichloronickel(II)

Description:
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) is a coordination compound featuring a nickel center coordinated to two chloride ions and a bidentate ligand derived from ferrocene. This compound is characterized by its unique structure, which includes a ferrocene moiety that provides stability and electronic properties due to its metallocene nature. The diphenylphosphino groups enhance the ligand's ability to stabilize the nickel center through strong σ-donation and π-acceptance. Typically, this compound exhibits a square planar geometry around the nickel(II) ion, which is common for d8 metal complexes. It is often used in catalysis and organometallic chemistry due to its ability to facilitate various chemical reactions, including cross-coupling processes. The presence of the ferrocene unit also imparts interesting electrochemical properties, making it a subject of study in materials science and molecular electronics. Additionally, the compound's solubility and reactivity can vary depending on the solvent and conditions, which are important factors in its application in synthetic chemistry.
Formula:C34H28Cl2FeNiP2
InChI:InChI=1/2C17H14P.2ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2
SMILES:c1ccc(cc1)P(c1ccccc1)C1=CC=C[CH]1.c1ccc(cc1)P(c1ccccc1)C1=CC=C[CH]1.Cl.Cl.[Fe].[Ni]
Synonyms:
  • (1,1'-Bis(Diphenylphosphino)Ferrocene)-Dichloroni
  • Dichlorobisdiphenylphosphinoferrocenenickel
  • [1,1-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
  • Dichloro[1,1-bis(diphenylphosphino)ferrocene]nickel(II)
  • 1,1'-Bis(Diphenylphosphino)Ferrocene Nickel Dichloride
  • 1,1'-Bis(diphenylphosphino)ferrocenedichloronickel
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]Nickle (II)
  • (DPPF)NiCl2
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