CAS 6867-30-7
:Lithium acetylide-ethylenediamine complex
Description:
Lithium acetylide-ethylenediamine complex, with the CAS number 6867-30-7, is a coordination compound formed between lithium acetylide and ethylenediamine. This complex typically exhibits characteristics associated with both its components. Lithium acetylide is known for its strong nucleophilic properties and is often used in organic synthesis, particularly in the formation of carbon-carbon bonds. The presence of ethylenediamine, a bidentate ligand, enhances the solubility and stability of the complex in various solvents. The coordination of ethylenediamine to lithium acetylide can influence the reactivity and selectivity of the acetylide anion in chemical reactions. Additionally, this complex may exhibit unique spectroscopic properties, such as shifts in infrared or NMR spectra, due to the interactions between the lithium ion and the nitrogen atoms of ethylenediamine. Overall, the lithium acetylide-ethylenediamine complex serves as a valuable reagent in synthetic organic chemistry, particularly in reactions requiring a strong base or nucleophile.
Formula:C4H9LiN2
InChI:InChI=1S/C2H8N2.C2H.Li/c3-1-2-4;1-2;/h1-4H2;1H;/q;-1;+1
InChI key:InChIKey=WMWSRIHFAVOHSW-UHFFFAOYSA-N
SMILES:[C-](#C)[Li+]1[NH2]CC[NH2]1
Synonyms:- (1,2-Diaminoethane)(ethynyl)lithium
- (1,2-Ethanediamine-N,N′)ethynyllithium
- (1,2-Ethanediamine-κN<sup>1</sup>,κN<sup>2</sup>)ethynyllithium
- (Acetylido)(ethylenediamine)lithium
- Ethane-1,2-Diamine
- Ethylenediamine compd. with Li acetylide
- Ethylenediamine, compd. with lithium acetylide (Li(HC<sub>2</sub>)) (1:1)
- Ethynyl lithium-ethylene diamine complex
- Ethynyllithium
- Ethynyllithium complex with 1,2-ethanediamine (1:1)
- Lithium acetylide (Li(HC<sub>2</sub>)), compd. with ethylenediamine (1:1)
- Lithium acetylide ethylenediamine complex
- Lithium acetylide-ethylenediamine (1:1)
- Lithium, (1,2-ethanediamine-N,N′)ethynyl-
- Lithium, (1,2-ethanediamine-κN,κN′)ethynyl-
- Lithium, (1,2-ethanediamine-κN<sup>1</sup>,κN<sup>2</sup>)ethynyl-
- Lithium acetylide (Li(HC2)), compd. with ethylenediamine (1:1)
- Lithium, (1,2-ethanediamine-κN1,κN2)ethynyl-
- See more synonyms
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Found 2 products.
Lithium acetylide ethylenediamine complex, tech. 85%
CAS:Lithium acetylide ethylenediamine complex is used in the synthesis of a chiral cyclopropanol. It is also used as an alkynylating reagent for the enantioselective alkynylation of ketones catalyzed by lithium binaphtholate without using other metal sources. This Thermo Scientific Chemicals brand produ
Formula:C4H9LiN2Purity:85%Color and Shape:Pale yellow to brown to grey-brown, Crystals or powder or crystalline powderMolecular weight:92.07Lithium acetylide ethylenediamine complex
CAS:Formula:C4H9LiN2Purity:≥ 90%Color and Shape:Colourless to yellow or brown crystalsMolecular weight:92.07

