CAS 70987-78-9
:(S)-Glycidyl tosylate
Description:
(S)-Glycidyl tosylate, with the CAS number 70987-78-9, is an organic compound characterized by its epoxide structure, which features a three-membered cyclic ether. This compound is typically used as a reactive intermediate in organic synthesis, particularly in the preparation of various chiral compounds due to its stereogenic center. It is a colorless to pale yellow liquid that is soluble in organic solvents but has limited solubility in water. The tosylate group enhances its reactivity, making it a useful electrophile in nucleophilic substitution reactions. Additionally, (S)-Glycidyl tosylate can participate in ring-opening reactions, allowing for the introduction of various nucleophiles, which is valuable in the synthesis of pharmaceuticals and agrochemicals. Safety considerations include handling it in a well-ventilated area and using appropriate personal protective equipment, as it may be irritating to the skin and eyes. Overall, its unique structural features and reactivity make it a significant compound in synthetic organic chemistry.
Formula:C10H12O4S
InChI:InChI=1S/C10H12O4S/c1-8-2-4-10(5-3-8)15(11,12)14-7-9-6-13-9/h2-5,9H,6-7H2,1H3/t9-/m0/s1
InChI key:InChIKey=NOQXXYIGRPAZJC-VIFPVBQESA-N
SMILES:S(OC[C@@H]1CO1)(=O)(=O)C2=CC=C(C)C=C2
Synonyms:- (+)-Glycidyl tosylate
- (2S)-(+)-Glycidyl Tosylate
- (2S)-Glycidyl toslyate
- (2S)-Oxiranemethanol 4-methylbenzenesulfonate
- (S)-(+)-Glycidyl 4-methylbenzenesulfonate
- (S)-(2,3-Epoxypropan-1-yl) 4-methylbenzenesulfonate
- (S)-Glycidol tosylate
- (S)-Glycidyl p-toluenesulfonate
- (S)-Oxiranylmethyl toluene-4-sulfonate
- (S)-Toluene-4-sulfonic acid oxiranylmethyl ester
- 2(S)-Glycidyl tosylate
- 2-Oxiranemethanol, 2-(4-methylbenzenesulfonate), (2S)-
- Oxiranemethanol, 4-methylbenzenesulfonate, (2S)-
- Oxiranemethanol, 4-methylbenzenesulfonate, (S)-
- S-Glycidyl Tosylate
- Toluene-4-sulfonic acid (S)-oxiranylmethyl ester
- [(2S)-Oxiran-2-yl]methyl 4-methylbenzene-1-sulfonate
- See more synonyms
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Found 9 products.
(2S)-(+)-Glycidyl p-Toluenesulfonate
CAS:Formula:C10H12O4SPurity:>98.0%(GC)Color and Shape:White to Almost white powder to crystalMolecular weight:228.26(2S)-(+)-Glycidyl tosylate
CAS:Formula:C10H12O4SPurity:98%Color and Shape:SolidMolecular weight:228.2649(S)-Glycidyl tosylate
CAS:Controlled ProductFormula:C10H12O4SColor and Shape:NeatMolecular weight:228.26(2S)-Oxiran-2-ylmethyl 4-methylbenzenesulphonate
CAS:<p>(2S)-Oxiran-2-ylmethyl 4-methylbenzenesulphonate</p>Purity:98%Molecular weight:228.26g/mol(2S)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
CAS:Formula:C10H12O4SPurity:98%Color and Shape:White to Yellow SolidMolecular weight:228.26(2S)-(+)-Glycidyl Tosylate
CAS:Controlled Product<p>Applications Protected Glycidol, used as an intermediate in the preparation of neurochemicals.<br>References Wang, J., et al.: J. Med. Chem., 48, 6271 (2005), Qian, L., et al.: ChemMedChem, 1, 376 (2006), Li, Y., et al.: Bioorg. Med. Chem. Lett., 19, 5037 (2009),<br></p>Formula:C10H12O4SColor and Shape:Off-WhiteMolecular weight:228.26S-(+)-Glycidyl tosylate
CAS:<p>S-(+)-Glycidyl tosylate is a cross-linking agent that can be used in the preparation of polymers. It has been shown to react with epoxides and hydroxyl groups, but not with hydroxy groups. S-(+)-Glycidyl tosylate is also considered a nucleophilic reagent that reacts with nucleophiles such as amines, alcohols, and thiols. This product is an enantiomer of racemic glycidyl tosylate, which is a reaction intermediate for the synthesis of epoxy resins. The use of this product may lead to the production of hard and brittle materials due to its ability to form strong covalent bonds. S-(+)-Glycidyl tosylate was first synthesized by reacting ethylene oxide with chloroacetic acid followed by hydrolysis of the resulting chloroacetaldehyde ester using an acid catalyst. The isolated</p>Formula:C10H12O4SPurity:Min. 95%Color and Shape:PowderMolecular weight:228.27 g/mol
