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CAS 71042-55-2

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1,1′-[(1R,2R,3R,4S)-Bicyclo[2.2.1]hept-5-ene-2,3-diyl]bis[1,1-diphenylphosphine]

Description:
1,1′-[(1R,2R,3R,4S)-Bicyclo[2.2.1]hept-5-ene-2,3-diyl]bis[1,1-diphenylphosphine], with CAS number 71042-55-2, is a complex organophosphorus compound characterized by its unique bicyclic structure and the presence of diphenylphosphine groups. This compound features a bicyclo[2.2.1]heptene core, which contributes to its rigidity and steric properties, making it an interesting candidate for various chemical applications, particularly in catalysis and coordination chemistry. The diphenylphosphine moieties enhance its reactivity and solubility in organic solvents, while also providing potential sites for coordination with metal centers. The stereochemistry of the bicyclic framework imparts specific spatial arrangements that can influence the compound's reactivity and interaction with other molecules. Overall, this substance is notable for its potential use in asymmetric synthesis and as a ligand in transition metal complexes, showcasing the interplay between its structural features and chemical behavior.
Formula:C31H28P2
InChI:InChI=1S/C31H28P2/c1-5-13-26(14-6-1)32(27-15-7-2-8-16-27)30-24-21-22-25(23-24)31(30)33(28-17-9-3-10-18-28)29-19-11-4-12-20-29/h1-22,24-25,30-31H,23H2/t24-,25+,30-,31-/m1/s1
InChI key:InChIKey=CDJHPMXMJUCLPA-RMDVPPNSSA-N
SMILES:P([C@H]1[C@H]([P@@](C2=CC=CC=C2)C3=CC=CC=C3)[C@@]4(C[C@]1(C=C4)[H])[H])(C5=CC=CC=C5)C6=CC=CC=C6
Synonyms:
  • Phosphine, bicyclo[2.2.1]hept-5-ene-2,3-diylbis[diphenyl-, [1S-(2-endo,3-exo)]-
  • Phosphine, (1R,2R,3R,4S)-bicyclo[2.2.1]hept-5-ene-2,3-diylbis[diphenyl-
  • 1,1′-[(1R,2R,3R,4S)-Bicyclo[2.2.1]hept-5-ene-2,3-diyl]bis[1,1-diphenylphosphine]
  • Phosphine, 1,1′-[(1R,2R,3R,4S)-bicyclo[2.2.1]hept-5-ene-2,3-diyl]bis[1,1-diphenyl-
  • Norphos, (-)-
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