CAS 71423-54-6

(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Description:

(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, commonly referred to as a rhodium complex, is a chiral organometallic compound notable for its application in asymmetric catalysis. This compound features a rhodium(I) center coordinated to a bidentate phosphine ligand, which enhances its reactivity and selectivity in catalytic reactions, particularly in the hydrogenation and hydroformylation of alkenes. The presence of the tetrafluoroborate counterion contributes to the solubility and stability of the complex in various solvents. The specific stereochemistry of the (S,S) configuration is crucial for its catalytic properties, allowing for the preferential formation of one enantiomer over another in reactions. Additionally, the o-methoxyphenyl groups provide steric and electronic effects that further influence the reactivity of the rhodium center. Overall, this compound exemplifies the intricate relationship between molecular structure and catalytic performance in organometallic chemistry.

Synonyms:

• (S,S)-1,2-Ethanediyl-Bis-[(2-Methoxyphenyl)-Phenylphosphine]]-(1,5-Cyclooctadiene)-Rhodium(I)]-Tetrafluoroborate

(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%

CAS: 71423-54-6

(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%

Formula: Rh(C₈H₁₂)(C₂₈H₂₈O₂P₂)BF₄

Purity: min. 95%

Color and Shape: orange pwdr.

Molecular weight: 756.38

Ref: 08-45-0226