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CAS 74311-56-1

:

(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine

Description:
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine is a chiral organometallic compound notable for its application in asymmetric catalysis. This compound features a ferrocenyl moiety, which contributes to its stability and unique electronic properties, making it useful in various catalytic processes. The presence of two diphenylphosphino groups enhances its coordination ability with transition metals, facilitating the formation of metal complexes that are effective in promoting enantioselective reactions. The dimethylamino group provides solubility in organic solvents and can influence the steric and electronic environment around the metal center. As a chiral ligand, it can induce chirality in substrates during catalytic transformations, making it valuable in the synthesis of enantiomerically pure compounds. The compound's stereochemistry, indicated by the (R) and (S) designations, is crucial for its reactivity and selectivity in chemical reactions. Overall, this substance exemplifies the intersection of organometallic chemistry and asymmetric synthesis, showcasing the importance of chirality in modern chemical applications.
Formula:C38H37FeNP2
InChI:InChI=1/C21H23NP.C17H14P.Fe/c1-17(22(2)3)20-15-10-16-21(20)23(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h4-17H,1-3H3;1-14H;/t17-;;/m1../s1
SMILES:C[C@H](C1C=CC=C1P(c1ccccc1)c1ccccc1)N(C)C.c1ccc(cc1)P(c1ccccc1)C1=CC=C[CH]1.[Fe]
Synonyms:
  • (R)-N,N-Dimethyl-1-[(S)-1,2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • (-)-(R)-N,N-dimethyl-1-((S)-1,2-bis-*(diphenyl-
  • 1,2,3,4,5-cyclopentanepentayl, 1-[(1R)-1-(dimethylamino)ethyl]-2-(diphenylphosphino)-, compd. with 1-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1)
  • (R)-(S)-Bppfa
  • (R)-N,N-Dimethyl-1-((S)-1',2-bis(diphenylphosphino
  • [r,r]-1-[1-dimethylaminoethyl]-1',2-bis[diphenylphosphino]ferrocene
  • (R)-N,N-DIMETHYL-1-[(S)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine,98%
  • )-(R)-N,N-Dimethyl-1-[(S)-1
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine&gt
  • See more synonyms
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