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CAS 75777-87-6

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Tris[4,4'-di-tert-butyl-(2,2')-bipyridine]ruthenium(II) dihexafluorophosphate

Description:
Tris[4,4'-di-tert-butyl-(2,2')-bipyridine]ruthenium(II) dihexafluorophosphate, commonly referred to as Ru(bdtbpy)3(PF6)2, is a coordination complex featuring ruthenium as the central metal ion coordinated to three bidentate ligands, 4,4'-di-tert-butyl-(2,2')-bipyridine. This compound is characterized by its robust stability and solubility in polar organic solvents, making it suitable for various applications in photochemistry and electrochemistry. The bulky tert-butyl groups enhance the solubility and steric hindrance, which can influence the electronic properties of the complex. The hexafluorophosphate anion serves as a counterion, contributing to the overall stability of the compound. Ru(bdtbpy)3(PF6)2 exhibits interesting photophysical properties, including strong absorption in the visible region and efficient luminescence, making it a candidate for use in light-harvesting systems, sensors, and as a catalyst in various chemical reactions. Its redox-active nature allows for potential applications in molecular electronics and photoredox catalysis.
Formula:C54H72F12N6RuP2
Synonyms:
  • Tris[4,4'-di-tert-butyl-(2,2')-bipyridine]ruthenium(III) dihexafluorophosphate
  • Tris[4,4'-bis(t-butyl)-2,2'-bipyridine]ruthenium(II) hexafluorophosphate, 95%
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