CAS 762-72-1

Allyltrimethylsilane

Description:

Allyltrimethylsilane is an organosilicon compound characterized by the presence of a trimethylsilyl group attached to an allyl group. Its molecular formula is C6H14OSi, and it features a silicon atom bonded to three methyl groups and one allyl group, which consists of a vinyl group (–CH=CH2) connected to a methylene group (–CH2–). This compound is typically a colorless liquid with a distinctive odor and is known for its reactivity in various organic synthesis reactions, particularly in the formation of carbon-carbon bonds. Allyltrimethylsilane is often utilized as a reagent in organic chemistry, especially in reactions involving nucleophilic substitutions and as a protecting group for alcohols. Its silicon atom provides unique properties, such as enhanced stability and the ability to participate in cross-coupling reactions. Additionally, it is soluble in organic solvents, making it versatile for various applications in synthetic chemistry. Safety precautions should be observed when handling this compound, as it may pose health risks if inhaled or ingested.

Formula: C₆H₁₄Si

InChI: InChI=1S/C6H14Si/c1-5-6-7(2,3)4/h5H,1,6H2,2-4H3

InChI key: InChIKey=HYWCXWRMUZYRPH-UHFFFAOYSA-N

SMILES: C([Si](C)(C)C)C=C

Synonyms:

• 3-(Trimethylsilyl)-1-propene
• 3-(Trimethylsilyl)propene
• Aliltrimetilsilano
• Allyl(trimethyl)silane
• Allyltrimethylisilane
• Allyltrimethylsilan
• Allytrimethylsilane
• Sia 0555.0
• Silane, allyltrimethyl-
• Silane, trimethyl-2-propen-1-yl-
• Silane, trimethyl-2-propenyl-
• Trimethyl(2-propenyl)silane
• Trimethyl(Prop-2-En-1-Yl)Silane
• Trimethyl-2-propen-1-ylsilane
• Trimethyl-prop-2-enylsilane
• Trimethylallylsilane
• Trimethylsilane, Allyl-

Allyltrimethylsilane

CAS: 762-72-1

Formula: C₆H₁₄Si

Purity: >98.0%(GC)

Color and Shape: Colorless to Almost colorless clear liquid

Molecular weight: 114.26

Ref: 3B-A0729

Allyltrimethylsilane, 98+%

CAS: 762-72-1

Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement. This Thermo Scientific Chemicals br

Formula: C₆H₁₄Si

Purity: 98+%

Color and Shape: Clear colorless, Liquid

Molecular weight: 114.26

Ref: 02-A14662

Allyltrimethylsilane

CAS: 762-72-1

Allyltrimethylsilane

Molecular weight: 114.26086g/mol

Ref: 54-OR1021959

Allyltrimethylsilane

CAS: 762-72-1

Formula: CH₂CHCH₂Si(CH₃)₃

Purity: ≥ 97.0%

Color and Shape: Clear, colourless to light yellow liquid

Molecular weight: 114.27

Ref: 7W-GK0229

Allyltrimethylsilane

CAS: 762-72-1

S00450 - Allyltrimethylsilane

Formula: C₆H₁₄Si

Purity: 98%

Color and Shape: Liquid

Molecular weight: 114.263

Ref: 10-S00450

Allyltrimethylsilane

Controlled Product

CAS: 762-72-1

Stability Volatile
Applications Allyltrimethylsilane is used in the allylation of aldehydes, imines, allylic and benzylic alcohols, and chiral α-keto-amides that are derived from (S)-proline esters.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Yadav, J.S., et al.: Tetrahedron Lett., 43, 3783 (2002); Aggarwal, V.K., et al.: Tetrahedron Lett., 37, 3745 (1996); Wang, D.K., et al.: J. Org. Chem., 64, 4233 (1999); Kaur, G., et al.: Tetrahedron Lett., 38, 2521 (1997); Soai, K., et al.: J. Chem. Soc., Chem. Commun., 15, 1016 (1984)

Formula: C₆H₁₄Si

Color and Shape: Neat

Molecular weight: 114.26

Ref: TR-A572350