CAS 84680-95-5

1,1'-Bis(di-tert-butylphosphino)ferrocene

Description:

1,1'-Bis(di-tert-butylphosphino)ferrocene is a bimetallic organophosphorus compound characterized by its unique structure, which features a ferrocene backbone substituted with two di-tert-butylphosphino groups. This compound exhibits notable stability and solubility in organic solvents, making it useful in various chemical applications, particularly in catalysis and coordination chemistry. The presence of the bulky tert-butyl groups enhances steric hindrance, which can influence the reactivity and selectivity of the compound in catalytic processes. Additionally, the ferrocene moiety contributes to its redox properties, allowing for potential applications in electrochemistry. The phosphine ligands can coordinate to transition metals, facilitating the formation of metal complexes that are valuable in organic synthesis and materials science. Overall, 1,1'-Bis(di-tert-butylphosphino)ferrocene is recognized for its versatility and effectiveness in enhancing the performance of catalysts in various chemical reactions.

Formula: C₂₆H₄₂FeP₂

InChI: InChI=1/2C13H21P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-9H,1-6H3;/q2*-1;+2/rC26H42FeP2/c1-23(2,3)28(24(4,5)6)21-17-13-15-19(21)27-20-16-14-18-22(20)29(25(7,8)9)26(10,11)12/h13-18H,1-12H3

SMILES: CC(C)(C)P(C1=C=C[CH-][CH]1)C(C)(C)C.CC(C)(C)P(C1=C=C[CH-][CH]1)C(C)(C)C.[Fe]

Synonyms:

• 1,1'-Bis(di-t-butylphosphino)ferrocene
• Bis(2-Ditert-Butylphosphanyl-1-Cyclopenta-2,4-Dienyl)Iron
• DtBPF

1,1'-Bis(di-tert-butylphosphino)ferrocene

CAS: 84680-95-5

Formula: C₂₆H₄₄FeP₂

Purity: >95.0%(T)

Color and Shape: Orange to Amber to Dark red powder to crystal

Molecular weight: 474.43

Ref: 3B-B2711

1,1'-Bis(di-tert-butylphosphino)ferrocene, 98%

CAS: 84680-95-5

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some docume

Formula: C₂₆H₄₄FeP₂

Purity: 98%

Color and Shape: Orange to orange-brown, Crystalline powder

Molecular weight: 474.43

Ref: 02-L19759

1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF

CAS: 84680-95-5

1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF

Formula: (C₄H₉)₂PC₅H₄Fe

Purity: min. 98%

Color and Shape: orange to red xtl.

Molecular weight: 474.42

Ref: 08-26-0150

1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene

CAS: 84680-95-5

Formula: C₂₆H₄₄FeP₂

Purity: 95%

Color and Shape: Solid

Molecular weight: 474.4201

Ref: IN-DA0032JO

1,1'-Bis(di-tert-butylphosphino)ferrocene

CAS: 84680-95-5

1,1'-Bis(di-tert-butylphosphino)ferrocene

Formula: C₂₆H₄₄FeP₂

Purity: 98%

Color and Shape: very dark red/brown solid

Molecular weight: 474.42g/mol

Ref: 54-OR16471

DTBPF

CAS: 84680-95-5

Purity: 95%

Color and Shape: Solid

Molecular weight: 474.23

Ref: 10-F996235

1,1'-Bis(di-tert-butylphosphino)ferrocene

Controlled Product

CAS: 84680-95-5

1,1'-Bis(di-tert-butylphosphino)ferrocene (BTPF) is an organophosphorus compound that is soluble in organic solvents. It is a catalyst for the conversion of terminal alkynes to 1,2-diols or alcohols. BTPF has been shown to react with chloride ions to produce the corresponding phosphine oxide species. This reaction proceeds via a free radical mechanism and can be used as a means of preparing phosphine oxides from chloride salts. BTPF crystallizes in centrosymmetrical space group P2/n with cell dimensions a=13.4 Å, b=13 Å, c=6.9 Å, β=105° and Z=8. The crystal structure consists of two interpenetrating ferrocene molecules that are linked by one monodentate diphosphine ligand in each molecule and one bridging diph

Formula: C₁₃H₂₃P·Fe

Purity: Min. 95%

Molecular weight: 476.45 g/mol

Ref: 3D-FB10602