CAS 849925-12-8

(1S,1′S)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(S)-(dimethylamino)phenylmethyl]ferrocene

Description:

The chemical substance known as "(1S,1′S)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(S)-(dimethylamino)phenylmethyl]ferrocene" with CAS number 849925-12-8 is a complex organophosphorus compound featuring a ferrocene backbone. This compound is characterized by its chiral centers, which contribute to its stereochemistry and potential applications in asymmetric synthesis. The presence of multiple phosphine groups enhances its reactivity and makes it a valuable ligand in coordination chemistry, particularly in catalysis. The methoxy and dimethylamino substituents on the phenyl rings provide additional electronic effects, influencing the compound's properties and reactivity. Its unique structure allows for interactions with transition metals, making it useful in various catalytic processes, including cross-coupling reactions. The compound's stability and solubility can vary based on the solvent and conditions, which are important factors to consider in practical applications. Overall, this substance exemplifies the intricate design of ligands in organometallic chemistry, showcasing the interplay between structure and function.

Formula: C₆₄H₇₄FeN₂O₄P₂

InChI: InChI=1S/2C32H37NO2P.Fe/c2*1-21-17-26(18-22(2)31(21)34-7)36(27-19-23(3)32(35-8)24(4)20-27)29-16-12-15-28(29)30(33(5)6)25-13-10-9-11-14-25;/h2*9-20,30H,1-8H3;/q2*-1;+2/t2*30-;/m00./s1

InChI key: InChIKey=HPUIPHVXVUIUDU-RELFUISISA-N

SMILES: P([C-]12[Fe+2]3456789([C-]%10(P(C%11=CC(C)=C(OC)C(C)=C%11)C%12=CC(C)=C(OC)C(C)=C%12)C3([C@@H](N(C)C)C%13=CC=CC=C%13)=C4([CH]5=C6%10[H])[H])C1([C@@H](N(C)C)C%14=CC=CC=C%14)=[CH]7C8(=C92[H])[H])(C%15=CC(C)=C(OC)C(C)=C%15)C%16=CC(C)=C(OC)C(C)=C%16

Synonyms:

• SL-M004-2
• Ferrocene, 1,1′-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(S)-(dimethylamino)phenylmethyl]-, (1S,1′S)-
• (1S,1′S)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(S)-(dimethylamino)phenylmethyl]ferrocene

(RP,R′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(S)-α-(dimethylamino)benzyl]ferrocene

CAS: 849925-12-8

Formula: C₆₄H₇₂FeN₂O₄P₂

Purity: 98%

Color and Shape: Solid

Molecular weight: 1051.0600

Ref: IN-DA003CCW

(1Rp,1'Rp)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(S)-(dimethylamino)phenylmethyl]ferrocene

CAS: 849925-12-8

(1Rp,1'Rp)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(S)-(dimethylamino)phenylmethyl]ferrocene

Purity: 97%

Molecular weight: 1053.1g/mol

Ref: 54-IN12648

Mandyphos SL-M004-2

CAS: 849925-12-8

Purity: 98%

Molecular weight: 1092.57

Ref: 10-F556573