CAS 849950-56-7

[Rh COD (R)-Phanephos]BF4, Rh 11.8%

Description:

The chemical substance "[Rh COD (R)-Phanephos]BF4" is a rhodium complex that features a rhodium center coordinated to cyclooctadiene (COD) and a chiral phosphine ligand known as (R)-Phanephos. This complex is notable for its application in asymmetric catalysis, particularly in reactions such as hydrogenation and other transformations where chirality is essential. The presence of the tetrafluoroborate (BF4) counterion contributes to the solubility and stability of the complex in various solvents. The rhodium content of 11.8% indicates a significant proportion of the metal, which is crucial for its catalytic activity. As a transition metal complex, it exhibits properties typical of coordination compounds, including distinct electronic and steric characteristics that influence its reactivity. The chiral nature of the phosphine ligand allows for the induction of asymmetry in chemical reactions, making it valuable in the synthesis of enantiomerically enriched compounds. Overall, this compound is of interest in both academic research and industrial applications in the field of organic synthesis.

Formula: C₄₈H₄₆BF₄P₂Rh

Synonyms:

• (R)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, Min. 97%
• [Rh COD (R)-Phanephos]BF4, Rh 11.8%

(R)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%

CAS: 849950-56-7

(R)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%

Formula: C₄₈H₄₆BF₄P₂Rh

Purity: min. 97%

Color and Shape: yellow-orange solid

Molecular weight: 874.54

Ref: 08-45-0217

Rhodium(1+), [(1,2,5,6-h)-1,5-cyclooctadiene][tricyclo[8.2.2.24,7]hexadeca-4,6,10,12, 13,15-hexaene-5,11-diylbis[diphenylphosphine-kP]]-, tetrafluoroborate(1-)

CAS: 849950-56-7

Rhodium(1+), [(1,2,5,6-h)-1,5-cyclooctadiene][tricyclo[8.2.2.24,7]hexadeca-4,6,10,12, 13,15-hexaene-5,11-diylbis[diphenylphosphine-kP]]-, tetrafluoroborate(1-)

Purity: 97%

Molecular weight: 872.54g/mol

Ref: 54-IN12645

Rhodium(1+), [(1,2,5,6-h)-1,5-cyclooctadiene][tricyclo[8.2.2.24,7]hexadeca-4,6,10,12, 13,15-hexaene-5,11-diylbis[diphenylphosphine-kP]]-, tetrafluoroborate(1-)

CAS: 849950-56-7

Formula: C₄₈H₄₆BF₄P₂Rh

Purity: 97%

Color and Shape: Solid

Molecular weight: 874.5364748000004

Ref: IN-DA00G533