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CAS 852445-82-0

:

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]chlorogold

Description:
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]chlorogold, with the CAS number 852445-82-0, is a gold complex that features a unique imidazolidinylidene ligand. This compound is characterized by its coordination of gold with a stable N-heterocyclic carbene (NHC) ligand, which enhances the stability and reactivity of the gold center. The presence of the bulky 2,4,6-trimethylphenyl groups contributes to steric hindrance, influencing its reactivity and solubility in organic solvents. This compound is often utilized in catalysis, particularly in organic transformations such as cross-coupling reactions and as a catalyst in various organic synthesis processes. Its chlorogold moiety allows for potential reactivity with nucleophiles, making it a versatile reagent in synthetic chemistry. Additionally, the stability imparted by the NHC ligand makes it an attractive candidate for applications in materials science and nanotechnology. Overall, this compound exemplifies the intersection of organometallic chemistry and catalysis, showcasing the utility of gold complexes in modern synthetic methodologies.
Formula:C21H26AuClN2
InChI:InChI=1S/C21H26N2.Au.ClH/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;;/h9-12H,7-8H2,1-6H3;;1H/q;+1;/p-1
InChI key:InChIKey=LGBMTOBGVBJTKP-UHFFFAOYSA-M
SMILES:[Au](Cl)=C1N(CCN1C2=C(C)C=C(C)C=C2C)C3=C(C)C=C(C)C=C3C
Synonyms:
  • [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]chlorogold
  • Chloro(1,3-dimesitylimidazolidin-2-ylidene)gold
  • Gold, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]chloro-
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