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CAS 852445-83-1

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1,3-Bis(2,6-di-isopropylphenyl)imidazol-2-ylidene gold(I) chloride

Description:
1,3-Bis(2,6-di-isopropylphenyl)imidazol-2-ylidene gold(I) chloride, commonly referred to as a gold(I) complex, is a coordination compound featuring a gold center bonded to a stable N-heterocyclic carbene (NHC) ligand. The presence of the bulky 2,6-di-isopropylphenyl groups enhances the stability of the imidazolium ring, making it an effective ligand for gold. This compound typically exhibits a yellow to orange color and is soluble in organic solvents, which is characteristic of many gold complexes. It is known for its catalytic properties, particularly in organic synthesis, where it can facilitate various reactions such as cross-coupling and cyclization processes. The gold(I) center in this compound is in a low oxidation state, which contributes to its reactivity and ability to form complexes with other substrates. Additionally, the chloride ion serves as a counterion, balancing the charge of the complex. Overall, this compound is of significant interest in both academic research and industrial applications due to its unique properties and versatility in catalysis.
Formula:C27H36AuClN2
InChI:InChI=1/C27H36N2.Au.ClH/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;;1H/q;+1;/p-1/rC27H36AuClN2/c1-17(2)21-11-9-12-22(18(3)4)25(21)30-15-16-31(27(30)28-29)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3
Synonyms:
  • Bisdi-Isopropylphenyl)Imidazolylidene Gold(I) Chloride
  • Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)
  • [1,3-Bis(2,6-Diisopropylphenyl)Imidazol-2-Ylidene]-Chloro-Gold
  • 1,3-Bis(2,6-Di-Isopropylphenyl)Imidazol-2-Ylidenegold(I)Chloride
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