CAS 870987-63-6

4,4-Bis(tert-butyl)-2,2-bipyridine]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium(III)hexafluorophosphate

Description:

4,4-Bis(tert-butyl)-2,2-bipyridine]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium(III)hexafluorophosphate is a complex organometallic compound featuring iridium as the central metal atom. This compound is characterized by its intricate structure, which includes two bipyridine ligands that are heavily substituted with tert-butyl groups, enhancing its solubility and stability. The presence of difluoro and trifluoromethyl groups in the phenyl and pyridine moieties contributes to its electronic properties, making it suitable for applications in organic electronics and photonics. The hexafluorophosphate counterion provides ionic stability and solubility in polar solvents. This compound is notable for its potential use in light-emitting devices, such as organic light-emitting diodes (OLEDs), due to its favorable photophysical properties. Additionally, the presence of multiple fluorine atoms can influence the compound's reactivity and interaction with other materials, making it a subject of interest in advanced materials research. Overall, its unique structural features and electronic characteristics make it a valuable compound in the field of coordination chemistry and materials science.

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-κN)phenyl-κC]iridium(III) Hexafluorophosphate

CAS: 870987-63-6

Formula: C₄₂H₃₄F₁₆IrN₄P

Purity: >95.0%(HPLC)(qNMR)

Color and Shape: Light yellow to Yellow powder to crystal

Molecular weight: 1,121.93

Ref: 3B-D5817

(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%

CAS: 870987-63-6

(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%

Formula: Ir(C₁₈H₂₄N₂)(C₁₂H₅F₅N)₂PF₆

Purity: 99%

Color and Shape: yellow xtl.

Molecular weight: 1121.91

Ref: 08-77-0425

4,4-Bis(tert-butyl)-2,2-bipyridine]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium(III)hexafluorophosphate

CAS: 870987-63-6

Formula: C₄₂H₃₄F₁₆IrN₄P

Purity: 95%

Color and Shape: Solid

Molecular weight: 1121.9114

Ref: IN-DA019DRO

(Ir[dF(CF3)ppy]2(dtbpy))PF6

CAS: 870987-63-6

(Ir[dF(CF3)ppy]2(dtbpy))PF6

Formula: C₄₂H₃₆F₁₀IrN₄

Purity: 98%

Color and Shape: yellow solid

Molecular weight: 978.96307g/mol

Ref: 54-PC13675

Ir[dF(CF3)ppy]2(dtbbpy)PF6

CAS: 870987-63-6

Purity: 95%

Molecular weight: 1124.21

Ref: 10-F551860

[4,​4'-​Bis(tert-butyl)​-​2,​2'-​bipyridine]​bis[3,​5-​difluoro-​2-​[5-​(trifluoromethyl)​-​2-​pyridinyl]​phenyl]​iridium(III) hexafluorophosphate

Controlled Product

CAS: 870987-63-6

Applications [4,​4'-​Bis(tert-butyl)​-​2,​2'-​bipyridine]​bis[3,​5-​difluoro-​2-​[5-​(trifluoromethyl)​-​2-​pyridinyl]​phenyl]​iridium(III) hexafluorophosphate is commonly used as a catalyst in the synthesis of various compounds such as saturated N-​heterocycles from aldehydes, fosmidomycin analogue, and many more.
References Jindakun, C., et al.: Org. Lett. 20, 2071-75 (2018); Guo, T., et al.: Adv. Synth. Catal., 360, 1352-57 (2018); Abbas, S.Y., et al.: Org. Lett., 20, 868-71 (2018)

Formula: C₄₂H₃₄F₁₀IrN₄·F₆P

Color and Shape: Neat

Molecular weight: 976.95 + (144.96)

Ref: TR-B588600

(Ir[dF(CF3)ppy]2(dtbpy))PF6

CAS: 870987-63-6

Ir(dF(CF3)ppy)2 (dtbpy)PF6 is a photosensitizer that can be used in cycloaddition reactions. It is soluble in nonpolar solvents and can be used as a catalyst for cycloadditions involving uncharged substrates. Ir(dF(CF3)ppy)2 (dtbpy)PF6 has been shown to catalyze the transfer of an electron from a donor molecule to an acceptor molecule, which generates energy that can be transferred to the environment. This process is called "energy transfer."

Formula: C₄₂H₃₄F₁₆IrN₄P

Purity: Min. 95%

Molecular weight: 1,121.91 g/mol

Ref: 3D-VJB98763