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CAS 873297-19-9

:

[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]-chloro-silver

Description:
[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]-chloro-silver, commonly referred to as a silver complex, is a compound characterized by its coordination of silver with a specific imidazolium ligand. This compound typically exhibits a stable, neutral coordination complex due to the strong σ-donating ability of the imidazolium ligand, which enhances the stability of the silver center. The bulky diisopropylphenyl groups contribute to steric hindrance, influencing the reactivity and solubility of the complex. It is often utilized in catalysis, particularly in cross-coupling reactions, due to its ability to facilitate the transfer of silver ions in various organic transformations. The presence of the chloride ion in the complex can also play a role in its reactivity and interaction with other substrates. Overall, this compound exemplifies the intersection of organometallic chemistry and catalysis, showcasing the importance of ligand design in modulating the properties and reactivity of metal complexes.
Formula:C27H36AgClN2
InChI:InChI=1/C27H36N2.Ag.ClH/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;;1H/q;+1;/p-1/rC27H36AgClN2/c1-17(2)21-11-9-12-22(18(3)4)25(21)30-15-16-31(27(30)28-29)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3
Synonyms:
  • Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver
  • Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver(I)
  • Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver &gt
  • [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver(I) chloride
  • (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)silver(III) chloride
  • [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]chlorosilver
  • idene]siL
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