CAS 87413-09-0: Dess-Martin periodinane

Description:Dess-Martin periodinane (DMP) is a powerful and selective oxidizing agent widely used in organic chemistry for the oxidation of alcohols to carbonyl compounds, such as aldehydes and ketones. It is characterized by its stability, ease of handling, and mild reaction conditions, making it a preferred choice for many synthetic applications. DMP is a dark purple solid that is soluble in common organic solvents like dichloromethane and acetonitrile. The reagent operates through a mechanism involving the formation of an intermediate periodinane species, which facilitates the transfer of oxygen to the substrate. One of the notable advantages of DMP is its ability to oxidize primary alcohols to aldehydes without further oxidation to carboxylic acids, thus providing a high degree of selectivity. Additionally, it generates minimal byproducts, which simplifies purification processes. Overall, Dess-Martin periodinane is valued for its efficiency and versatility in organic synthesis, particularly in the preparation of complex molecules in pharmaceutical and materials chemistry.

Formula:C₁₃H₁₃IO₈

InChI:InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3

InChI key:InChIKey=NKLCNNUWBJBICK-UHFFFAOYSA-N

SMILES:O=C1OI(OC(=O)C)(OC(=O)C)(OC(=O)C)C=2C=CC=CC12

Synonyms:
(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
(1,1-Diacetoxy-3-oxo-1,2-benziodoxol-1-yl) acetate
1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
1,1,1-tris(acetyloxy)-1lambda~5~,2-benziodoxol-3(1H)-one
1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one
1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro-
Acetic acid, 1,1′,1′′-(3-oxo-1λ<sup>5</sup>-1,2-benziodoxol-1(3H)-ylidyne) ester
Dess-Martin Reagent
Dess-martin
Martin's reagent
See more synonyms
Reagents, Martin's
Triacetoxyperiodinane
Dess Martin Periodinane
Acetic acid, 1,1′,1′′-(3-oxo-1λ5-1,2-benziodoxol-1(3H)-ylidyne) ester
Dess-Martin periodinane

Found 13 products.

Product data	Purity	Price range	Estimated delivery
Dess-Martin Periodinane REF: 3B-D2045CAS: 87413-09-0	>95.0%(T)	57.00 €~261.00 €	Mon 21 Apr 25
Dess-Martin periodinane REF: 02-L15779CAS: 87413-09-0	- - -	To inquire	Tue 22 Apr 25
Dess-Martin Periodinane REF: 10-F011794CAS: 87413-09-0	97.0%	29.00 €~443.00 €	Tue 22 Apr 25
(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one REF: IN-DA0035XKCAS: 87413-09-0	97%	21.00 €~286.00 €	Mon 28 Apr 25
Dess-Martin periodinane REF: 54-OR14263CAS: 87413-09-0	By gc: 99.14% (conversion of (Typical Value in Batch COA)	42.00 €~236.00 €	Tue 29 Apr 25
Dess-Martin Periodinane REF: 7W-GE1466CAS: 87413-09-0	≥ 98.0%	29.00 €~201.00 €	Tue 29 Apr 25
Dess-Martin Periodinane (8-12% in Dichloromethane) REF: 3B-D4477CAS: 87413-09-0	- - -	95.00 €~516.00 €	Tue 29 Apr 25
Dess-Martin periodinane, 15 wt.% solution in dichloromethane, AcroSeal™ REF: AC-42900CAS: 75-09-2 87413-09-0	- - -	To inquire	Tue 29 Apr 25
Dess-Martin periodinane, 15 wt.% solution in dichloromethane REF: AC-33311CAS: 75-09-2 87413-09-0	- - -	To inquire	Tue 29 Apr 25
Dess-Martin Periodinane (Technical Grade) REF: TR-D297420CAS: 87413-09-0	- - -	163.00 €~1,564.00 €	Tue 06 May 25
Dess-Martin periodinane REF: 3D-FD10776CAS: 87413-09-0	Min. 97 Area-%	To inquire	Wed 07 May 25
Dess-Martin periodinane - 15 wt.% solution in dichloromethane REF: 3D-FD168058CAS: 87413-09-0	- - -	- - -	Discontinued product
Dess Martin Periodinane extrapure, 97% REF: SR-43767CAS: 87413-09-0	min. 97%	- - -	Discontinued product