CAS 87413-09-0

Dess-Martin periodinane

Description:

Dess-Martin periodinane (DMP) is a powerful and selective oxidizing agent widely used in organic chemistry for the oxidation of alcohols to carbonyl compounds, such as aldehydes and ketones. It is characterized by its stability, ease of handling, and mild reaction conditions, making it a preferred choice for many synthetic applications. DMP is a dark purple solid that is soluble in common organic solvents like dichloromethane and acetonitrile. The reagent operates through a mechanism involving the formation of an intermediate periodinane species, which facilitates the transfer of oxygen to the substrate. One of the notable advantages of DMP is its ability to oxidize primary alcohols to aldehydes without further oxidation to carboxylic acids, thus providing a high degree of selectivity. Additionally, it generates minimal byproducts, which simplifies purification processes. Overall, Dess-Martin periodinane is valued for its efficiency and versatility in organic synthesis, particularly in the preparation of complex molecules in pharmaceutical and materials chemistry.

Formula: C₁₃H₁₃IO₈

InChI: InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3

InChI key: InChIKey=NKLCNNUWBJBICK-UHFFFAOYSA-N

SMILES: O(C(C)=O)I1(OC(C)=O)(OC(C)=O)C=2C(C(=O)O1)=CC=CC2

Synonyms:

• (1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
• (1,1-Diacetoxy-3-oxo-1,2-benziodoxol-1-yl) acetate
• 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
• 1,1,1-tris(acetyloxy)-1lambda~5~,2-benziodoxol-3(1H)-one
• 1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one
• 1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro-
• Acetic acid, 1,1′,1′′-(3-oxo-1λ⁵-1,2-benziodoxol-1(3H)-ylidyne) ester
• Dess-Martin Reagent
• Dess-martin
• Martin's reagent
• Reagents, Martin's
• Triacetoxyperiodinane
• Dess Martin Periodinane
• Acetic acid, 1,1′,1′′-(3-oxo-1λ5-1,2-benziodoxol-1(3H)-ylidyne) ester

Dess-Martin Periodinane

CAS: 87413-09-0

Formula: C₁₃H₁₃IO₈

Purity: >95.0%(T)

Color and Shape: White to Almost white powder to crystal

Molecular weight: 424.14

Ref: 3B-D2045

Dess-Martin Periodinane (8-12% in Dichloromethane)

CAS: 87413-09-0

Formula: C₁₃H₁₃IO₈

Color and Shape: Colorless to Light yellow clear liquid

Molecular weight: 424.14

Ref: 3B-D4477

Dess-Martin periodinane

CAS: 87413-09-0

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols. Th

Formula: C₁₃H₁₃IO₈

Color and Shape: White, Powder

Molecular weight: 424.14

Ref: 02-L15779

(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one

CAS: 87413-09-0

Formula: C₁₃H₁₃IO₈

Purity: 97%

Color and Shape: Solid

Molecular weight: 424.1420

Ref: IN-DA0035XK

Dess-Martin Periodinane

CAS: 87413-09-0

Formula: C₁₃H₁₃IO₈

Purity: ≥ 98.0%

Color and Shape: White to off-white powder or crystals

Molecular weight: 424.15

Ref: 7W-GE1466

Dess-Martin periodinane

CAS: 87413-09-0

Dess-Martin periodinane

Formula: C₁₃H₁₃IO₈

Purity: ≥95%

Color and Shape: white to off white powder

Molecular weight: 424.14198g/mol

Ref: 54-OR14263

Dess-Martin Periodinane

CAS: 87413-09-0

Formula: C₁₃H₁₃IO₈

Purity: 97.0%

Color and Shape: Crystals

Molecular weight: 424.143

Ref: 10-F011794

Dess-Martin Periodinane (Technical Grade)

Controlled Product

CAS: 87413-09-0

Applications Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Dess, D.B. et al.: J. Org. Chem., 48, 4155 (1983); Dess, D. B. et al.: J. Am. Chem. Soc., 113, 7277 (1991);

Formula: C₁₃H₁₃IO₈

Color and Shape: White To Beige

Molecular weight: 424.14

Ref: TR-D297420

Dess-Martin periodinane

CAS: 87413-09-0

Dess-Martin periodinane (DMP) is a chemoselective oxidant widely used in organic chemistry to oxidise primary alcohols to aldehydes and secondary alcohols to ketones. DMP is the acetylated version of another organic periodinane oxidant, 2-iodoxybenzoic acid (IBX). DMP has several advantages over IBX, namely higher solubility in common organic solvents, higher reactivity and longer shelf life.

Formula: C₁₃H₁₃IO₈

Purity: Min. 97 Area-%

Color and Shape: White Powder

Molecular weight: 424.14 g/mol

Ref: 3D-FD10776

Dess Martin Periodinane extrapure, 97%

CAS: 87413-09-0

Formula: C₁₃H₁₃IO₈

Purity: min. 97%

Color and Shape: White, Crystalline powder, Clear, Colourless

Molecular weight: 424.14

Ref: SR-43767