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CAS 884879-24-7

:

stereoisomer of [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-1-phenyl-2-propen-1-yl]palladium

Description:
The chemical substance known as "stereoisomer of [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-1-phenyl-2-propen-1-yl]palladium" with CAS number 884879-24-7 is a palladium complex that features a chiral imidazolidinylidene ligand. This compound is characterized by its coordination of palladium to a chloro ligand and a vinyl group, which is part of a more complex structure involving bulky aryl substituents. The presence of stereoisomerism indicates that the compound can exist in multiple spatial arrangements, which can significantly influence its reactivity and interaction with other molecules. Such palladium complexes are often utilized in catalysis, particularly in cross-coupling reactions and other organic transformations, due to their ability to facilitate the formation of carbon-carbon bonds. The steric hindrance provided by the bulky substituents enhances selectivity and can affect the overall efficiency of catalytic processes. Understanding the stereochemistry of this compound is crucial for optimizing its application in synthetic chemistry.
Formula:NeolystCX32
InChI:InChI=1S/C27H38N2.C9H9.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-2-6-9-7-4-3-5-8-9;;/h9-14,18-21H,15-16H2,1-8H3;2-8H,1H2;1H;/q-2;-1;;+4/p-1
InChI key:InChIKey=SWCINQFDTMPPRM-UHFFFAOYSA-M
SMILES:[Cl-][Pd+4]12([CH-]([CH]1=[CH2]2)C3=CC=CC=C3)=[C-2]4N(CCN4C5=C(C(C)C)C=CC=C5C(C)C)C6=C(C(C)C)C=CC=C6C(C)C
Synonyms:
  • Chloro[(1,2,3-N)-3-Phenyl-2-Propenyl][1,3-Bis(2,6-Di-I-Propylphenyl)-4,5-Dihydroimidazol-2-Ylidene]Palladium(Ii)
  • Chloro[(1,2,3-Η)-3-Phenyl-2-Propenyl][1,3-Bis(2,6-Di-I-Propylphenyl)-4,5-Dihydroimidazol-2-Ylidene]Palladium(II)
  • Palladium, [1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-1-phenyl-2-propen-1-yl]-, stereoisomer
  • Palladium, [1,3-bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-3-phenyl-2-propenyl]-, stereoisomer
  • Phenylallylchloro-[1,3-Bis(Diisopropylphenyl)-2-Imidazolidinylidene]Palladium(Ii)
  • Umicore CX32
  • stereoisomer of [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]chloro[(1,2,3-η)-1-phenyl-2-propen-1-yl]palladium
  • [1,3-Bis(2,6-di-isopropylphenyl)-4,5-dihydroimidazol-2-ylidene]chloro][3-phenylallyl]palladium(II) 95%
  • Chloro[(1,2,3-n)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)-4,
  • Chloro[(1,2,3-n)-3-phenyl-2-propenyl][1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II), min. 97%
  • See more synonyms
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