CymitQuimica logo

CAS 930796-10-4

:

7-[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]-7-chloro-8,8-dimethyl-8$l^{5}-aza-7$l^{5}-palladabicyclo[4.3.0]nona-1,3,5-triene

Description:
The chemical substance known as "7-[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]-7-chloro-8,8-dimethyl-8$l^{5}-aza-7$l^{5}-palladabicyclo[4.3.0]nona-1,3,5-triene" with CAS number 930796-10-4 is a complex organometallic compound featuring a palladium center. This compound is characterized by its unique bicyclic structure, which incorporates both imidazolium and aza functionalities, contributing to its potential reactivity and stability. The presence of bulky diisopropylphenyl groups enhances steric hindrance, which can influence its catalytic properties and selectivity in various chemical reactions. The chlorine substituent and the dimethyl groups further modify its electronic properties, making it suitable for applications in catalysis, particularly in cross-coupling reactions. The intricate design of this compound allows for specific interactions with substrates, making it a valuable candidate in synthetic organic chemistry. Its stability and reactivity are essential for its role in facilitating chemical transformations, showcasing the importance of ligand design in organometallic chemistry.
Formula:C36H48ClN3Pd
InChI:InChI=1/C27H36N2.C9H12N.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-10(2)8-9-6-4-3-5-7-9;;/h9-16,18-21H,1-8H3;3-6H,8H2,1-2H3;1H;/q;;;+1/p-1/rC36H48ClN3Pd/c1-24(2)29-16-13-17-30(25(3)4)34(29)38-21-22-39(35-31(26(5)6)18-14-19-32(35)27(7)8)36(38)41(37)33-20-12-11-15-28(33)23-40(41,9)10/h11-22,24-27H,23H2,1-10H3
SMILES:CC(C)c1cccc(C(C)C)c1N1#CN(C=C1)c1c(cccc1C(C)C)C(C)C.CN(C)Cc1ccccc1.Cl.[Pd]
Synonyms:
  • [1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene](chloro){2-[(dimethylamino-kappaN)methyl]phenyl-kappaC1
  • palladium, [1,3-bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene]chloro[2-[(dimethylamino-kappaN)methyl]phenyl-kappaC1
Sort by
Purity (%)
0
100
|
0
|
50
|
90
|
95
|
100
Found 3 products.