CAS 944450-48-0

(OC-6-22)-Bis(acetato-κO,κO′)[(4R)-1,1′-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-diphenylphosphine-κP]]ruthenium

Description:

The chemical substance known as "(OC-6-22)-Bis(acetato-κO,κO′)[(4R)-1,1′-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-diphenylphosphine-κP]]ruthenium" with CAS number 944450-48-0 is a complex organometallic compound featuring a ruthenium center coordinated to multiple ligands. Its structure includes two acetate groups that are coordinated through oxygen atoms, as well as a chiral ligand derived from a bi-1,3-benzodioxole framework, which contributes to its stereochemistry. The presence of diphenylphosphine ligands enhances its stability and reactivity, making it potentially useful in various catalytic applications, particularly in organic synthesis and materials science. The compound's unique architecture may also impart specific electronic and steric properties, influencing its behavior in chemical reactions. Additionally, the chirality of the ligand can lead to enantioselective processes, which are valuable in the synthesis of chiral molecules. Overall, this compound exemplifies the intricate design possible in coordination chemistry, with implications for both fundamental research and practical applications.

Formula: C₄₂H₃₄O₈P₂Ru

InChI: InChI=1S/C38H28O4P2.2C2H4O2.Ru/c1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;2*1-2(3)4;/h1-24H,25-26H2;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key: InChIKey=BHGLLIGZFQVMBJ-UHFFFAOYSA-L

SMILES: CC=1[O-][Ru+2]23([P](C=4C(C=5C([P]2(C6=CC=CC=C6)C7=CC=CC=C7)=CC=C8C5OCO8)=C9C(=CC4)OCO9)(C%10=CC=CC=C%10)C%11=CC=CC=C%11)([O-]C(C)=O3)O1

Synonyms:

• (OC-6-22)-Bis(acetato-κO,κO′)[(4R)-1,1′-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-diphenylphosphine-κP]]ruthenium
• R-Ru(OAc)2(SEGPHOS)
• Ruthenium, bis(acetato-κO,κO′)[(4R)-1,1′-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-diphenylphosphine-κP]]-, (OC-6-22)-

Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)₂[(R)-segphos®]

CAS: 944450-48-0

Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(R)-segphos®]

Formula: C₄₂H₃₄O₈P₂Ru

Color and Shape: dark yellow pwdr.

Molecular weight: 829.73

Ref: 08-44-0168

(R)-Ru(OAc)2(SEGPHOS)

CAS: 944450-48-0

Formula: C₄₂H₃₆O₈P₂Ru

Purity: 95%

Color and Shape: Solid

Molecular weight: 831.7480

Ref: IN-DA003CBX

Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)

CAS: 944450-48-0

Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)

Purity: 98%

Molecular weight: 829.73g/mol

Ref: 54-IN12404

Diacetato[(R)-(+)-5,5′-bis(diphenylphosphino)-4,4′-bi-1,3-benzodioxole]ruthenium(II)

CAS: 944450-48-0

Purity: 95%

Molecular weight: 830.08

Ref: 10-F551731