CAS 944450-50-4

(OC-6-22)-Bis(acetato-κO,κO′)[1,1′-(4S)-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]ruthenium

Description:

The chemical substance known as "(OC-6-22)-Bis(acetato-κO,κO′)[1,1′-(4S)-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]ruthenium" with CAS number 944450-50-4 is a complex organometallic compound featuring a ruthenium center coordinated with multiple ligands. Its structure includes bis(acetato) groups, which are acetate ligands that coordinate through oxygen atoms, and a bidentate phosphine ligand system that enhances its stability and reactivity. The presence of the bi-1,3-benzodioxole moiety contributes to its unique electronic properties, potentially influencing its catalytic behavior. This compound is of interest in various fields, including catalysis and materials science, due to its potential applications in organic synthesis and as a catalyst in chemical reactions. The specific stereochemistry indicated by the (4S) designation suggests that the compound may exhibit chiral properties, which can be significant in asymmetric synthesis. Overall, this ruthenium complex exemplifies the intricate design of organometallic compounds for targeted chemical applications.

Formula: C₅₀H₅₀O₈P₂Ru

InChI: InChI=1S/C46H44O4P2.2C2H4O2.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;2*1-2(3)4;/h9-24H,25-26H2,1-8H3;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key: InChIKey=ACKYBTAGKAINOG-UHFFFAOYSA-L

SMILES: CC=1[O-][Ru+2]23([P](C=4C(C=5C([P]2(C6=CC(C)=CC(C)=C6)C7=CC(C)=CC(C)=C7)=CC=C8C5OCO8)=C9C(=CC4)OCO9)(C%10=CC(C)=CC(C)=C%10)C%11=CC(C)=CC(C)=C%11)([O-]C(C)=O3)O1

Synonyms:

• (OC-6-22)-Bis(acetato-κO,κO′)[1,1′-(4S)-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]ruthenium
• Ruthenium, bis(acetato-κO,κO′)[1,1′-(4S)-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]-, (OC-6-22)-
• Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dm-segphos(R)]
• Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dm-segphos]
• (S)-Ru(OAc)2(DM-SEGPHOS)

(OC-6-22)-Bis(acetato-κO,κO′)[1,1′-(4S)-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]ruthenium

CAS: 944450-50-4

Formula: C₅₀H₅₀O₈P₂Ru

Purity: 98%

Color and Shape: Solid

Molecular weight: 941.9447

Ref: IN-DA003COB

Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)₂[(S)-dm-segphos®]

CAS: 944450-50-4

Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dm-segphos®]

Formula: C₅₀H₅₀O₈P₂Ru

Color and Shape: yellow to brownish-red to dark green solid

Molecular weight: 941.95

Ref: 08-44-0176

(S)-Ru(OAc)2(DM-SEGPHOS®)

CAS: 944450-50-4

Please enquire for more information about (S)-Ru(OAc)2(DM-SEGPHOS®) including the price, delivery time and more detailed product information at the technical inquiry form on this page

Formula: C₅₀H₅₀O₈P₂Ru

Purity: Min. 95%

Molecular weight: 941.94 g/mol

Ref: 3D-FR167803