CAS 944451-12-1

Ruthenate(1-), tri-μ-chlorodichlorobis[1,1′-[(1S)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[1,1-diphenylphosphine-κP]]di-, hydrogen, compd. with N-methylmethanamine (1:1:1)

Description:

Ruthenate(1-), tri-μ-chlorodichlorobis[1,1′-[(1S)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[1,1-diphenylphosphine-κP]]di-, hydrogen, compd. with N-methylmethanamine is a complex organometallic compound featuring a ruthenium center coordinated with multiple ligands, including phosphines and a chiral binaphthalene derivative. The presence of tri-μ-chlorodichloro ligands indicates a unique coordination environment, which can influence the compound's reactivity and stability. The compound's chirality, derived from the binaphthalene structure, may impart interesting optical properties and potential applications in asymmetric synthesis. Additionally, the inclusion of N-methylmethanamine suggests the formation of a stable adduct, which may enhance solubility and facilitate interactions in various chemical environments. Overall, this compound exemplifies the intricate interplay between metal coordination, ligand design, and stereochemistry, making it a subject of interest in the fields of catalysis and materials science.

Formula: C₈₈H₈₀Cl₅P₄Ru₂·C₂H₇N·H

InChI: InChI=1S/2C44H40P2.C2H7N.5ClH.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-12,19-26,29-32H,13-18,27-28H2;3H,1-2H3;5*1H;;/q;;;;;;;;2*+2/p-4

InChI key: InChIKey=VHWUKCMTKLMMGR-UHFFFAOYSA-J

SMILES: [Cl-][Ru+2]123([P](C=4C(C=5C([P]1(C6=CC=CC=C6)C7=CC=CC=C7)=CC=C8C5CCCC8)=C9C(=CC4)CCCC9)(C%10=CC=CC=C%10)C%11=CC=CC=C%11)[Cl-][Ru+2]%12([Cl-])([Cl-]2)([Cl-]3)[P](C=%13C(C=%14C([P]%12(C%15=CC=CC=C%15)C%16=CC=CC=C%16)=CC=C%17C%14CCCC%17)=C%18C(=CC%13)CCCC%18)(C%19=CC=CC=C%19)C%20=CC=CC=C%20.[H+].N(C)C

Synonyms:

• Ruthenate(1-), tri-μ-chlorodichlorobis[1,1′-[(1S)-5,5′,6,6′,7,7′,8,8′-octahydro[1,1′-binaphthalene]-2,2′-diyl]bis[1,1-diphenylphosphine-κP]]di-, hydrogen, compd. with N-methylmethanamine (1:1:1)

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH₂Me₂][{RuCl((S)-H₈-binap)}₂(μ-Cl)₃]

CAS: 944451-12-1

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-H8-binap)}2(μ-Cl)3]

Formula: (CH₃)₂NH₂C₈₈H₈₀Cl₅P₄Ru₂

Color and Shape: red-brown pwdr.

Molecular weight: 1685.96

Ref: 08-44-0517

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)

CAS: 944451-12-1

Formula: C₉₀H₉₁Cl₅NP₄Ru₂

Color and Shape: Solid

Molecular weight: 1691.0002

Ref: IN-DA003CII

(S)-[(RuCl(H8-BINAP))2(m-Cl)3][NH2Me2]

Controlled Product

CAS: 944451-12-1

Please enquire for more information about (S)-[(RuCl(H8-BINAP))2(m-Cl)3][NH2Me2] including the price, delivery time and more detailed product information at the technical inquiry form on this page

Purity: Min. 95%

Ref: 3D-FR175083