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CAS 944451-24-5

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Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl

Description:
Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride, commonly referred to as RuCl(p-cymene)((R)-xylbinap), is a coordination complex featuring ruthenium as the central metal atom. This compound is characterized by its chiral binaphthyl ligand, which imparts stereochemical properties that are significant in asymmetric catalysis. The presence of the p-cymene ligand enhances the solubility and reactivity of the ruthenium center. The complex typically exhibits a square planar geometry, which is common for d6 metal complexes, and it can participate in various catalytic reactions, particularly in the field of organic synthesis, such as hydrogenation and cross-coupling reactions. The di(3,5-xylyl)phosphino groups contribute to the electronic properties and steric bulk, influencing the reactivity and selectivity of the catalyst. Additionally, the chloride ligands can be replaced in reactions, allowing for the formation of more reactive species. Overall, this compound is notable for its applications in catalysis and its role in advancing synthetic methodologies in organic chemistry.
Formula:C62H62Cl2P2Ru
Synonyms:
  • Chloro{(R)-(+)-2,2'
  • cymene)(DM−
  • BINAP)]Cl
  • -binaphthyl}(p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((R)-xylbinap)]C
  • Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl
  • [RuCl(p-cymene)((R)-xylbinap)]Cl
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