CAS 944451-25-6

[1,1′-(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium

Description:

The chemical substance with the name "[1,1′-(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium" and CAS number "944451-25-6" is a complex organometallic compound featuring a ruthenium center coordinated with various ligands. This compound is characterized by its chiral binaphthalene backbone, which contributes to its stereochemical properties, making it potentially useful in asymmetric catalysis. The presence of bisphosphine ligands enhances its stability and reactivity, while the dichloro and η6-arene coordination provide additional electronic and steric properties. Such complexes are often studied for their catalytic applications in organic synthesis, particularly in reactions involving C-C bond formation. The intricate structure and the presence of bulky substituents suggest that it may exhibit unique reactivity patterns, making it a subject of interest in the field of coordination chemistry and catalysis. Overall, this compound exemplifies the intersection of organometallic chemistry and asymmetric synthesis.

Formula: C₆₂H₆₂Cl₂P₂Ru

InChI: InChI=1S/C52H48P2.C10H14.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-8(2)10-6-4-9(3)5-7-10;;;/h9-32H,1-8H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key: InChIKey=CBZXDZCPCDMKJU-UHFFFAOYSA-L

SMILES: [Cl-][Ru+2]123456([Cl-])(C=7(C(C)C)[CH]1=[CH]2C3(C)=[CH]4[CH]57)[P](C=8C(C=9C([P]6(C%10=CC(C)=CC(C)=C%10)C%11=CC(C)=CC(C)=C%11)=CC=C%12C9C=CC=C%12)=C%13C(=CC8)C=CC=C%13)(C%14=CC(C)=CC(C)=C%14)C%15=CC(C)=CC(C)=C%15

Synonyms:

• Ruthenium, [1,1′-(1S)-[1,1′-binaphthalene]-2,2′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-
• [1,1′-(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]dichloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium
• [RuCl(p-cymene)((S)-xylbinap)]Cl
• Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-xylbinap)]Cl

Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-xylbinap)]Cl

CAS: 944451-25-6

Formula: C₆₂H₆₀Cl₂P₂Ru

Purity: 98%

Color and Shape: Solid

Molecular weight: 1039.0633

Ref: IN-DA00IMK9

Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride

CAS: 944451-25-6

Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride

Purity: 98%

Molecular weight: 1039.06g/mol

Ref: 54-IN12694

Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-xylbinap)]Cl

CAS: 944451-25-6

Chloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-xylbinap)]Cl

Formula: C₆₂H₆₂ClP₂RuCl

Color and Shape: orange to brown pwdr.

Molecular weight: 1041.08

Ref: 08-44-0093

[RuCl(p-cymene)((S)-xylbinap)]Cl

CAS: 944451-25-6

Formula: C₆₂H₆₂Cl₂P₂Ru

Color and Shape: Light yellow to Brown powder to crystal

Molecular weight: 1,041.10

Ref: 3B-R0151